Polarization reversal behavior of spray deposited sodium nitrite:poly(vinyl alcohol) composite films Appl. Phys. Lett. 94, 102905 (2009); 10.1063/1.3098355 Domain stabilization effect of interlayer on ferroelectric poly(vinylidene fluoride-trifluoroethylene) copolymer ultrathin film Piezoresponse and ferroelectric properties of lead-free [ Bi 0.5 ( Na 0.7 K 0.2 Li 0.1 ) 0.5 ] Ti O 3 thin films by pulsed laser deposition Appl. Phys. Lett. 92, 222909 (2008); 10.1063/1.2938364 Study of ferroelectric properties in sodium nitrite:poly(vinyl alcohol) nanocomposite filmsThe composite films of sodium nitrite ͑NaNO 2 ͒ and poly͑vinyl alcohol͒ ͑PVA͒ have been deposited by spray technique at different substrate temperatures. The x-ray diffraction study revealed structural distortion ͑b / a ratio͒ in the composite films. The field-emission scanning electron microscopy images suggest that PVA polymer facilitate the homogeneous distribution of spherical grains of NaNO 2 with less porosity. The grain size is found to increase with the deposition temperature. The study of hysteresis loop characteristics gave optimum P r at deposition temperature of 200°C, which may be due to large structural distortion and less porosity. The back switching calculations and the switching characteristics indicate that 180°domains contribute more in the composite than the pure NaNO 2 film. The 1 / ⑀ 0 ͑dP / dE͒-E curves exhibit two coercive fields correspond to 180°and 90°domains. The composite film also showed improved fatigue characteristics.