“…[1,2] Shape memory polymers, as one class of typical representatives of smart polymeric materials, can memorize and recover to their shapes under external stimuli, such as heat, PH, light, and electric field, [3][4][5][6] which have been widely applied in many practical fields including aerospace, transportation, and biomedicine. [7][8][9] Self-healing polymers can be healed autonomously to restore some or all of the functions and mechanical behaviors, which would improve their service life, safety, and reliability. [10][11][12] Polylactic acid (PLA) is used as biological medical sutures and three-necked flask, which was then placed into ice water and stirred at 20 r min −1 for 30 min.…”