In
this work, we investigated the development of asphaltenes-triggered
two-layer wax deposit
with deposition time using an in-house wax deposition device, DSC,
HTGC, SARA, and microscopic observation. For the pure waxy oil (Waxy
Oil A), the formed wax deposit is a homogeneous and loose waxy oil
gel. The wax deposit mass is relatively high and increases with increasing
deposition time, while the wax appearance temperature (WAT), wax content,
and ΔW of the wax deposit are relatively low
and increase slowly with increasing deposition time. The critical
carbon number (CCN) of the wax deposit is C24. The precipitated wax
crystals (needlelike) in the wax deposit are liable to form a continuous
network structure, which is adverse for the diffusion of wax molecules.
The presence of asphaltenes in the pure waxy oil (Waxy Oils B–D)
causes the formation of a two-layer wax deposit, which can be clearly
characterized by the significant difference of structural strength.
Different from the outer-layer wax deposit, the inner-layer wax deposit
has smaller mass but higher WAT, wax content, CCN (C26), and asphaltene
content. The WAT and wax content of the inner-layer/outer-layer wax
deposits increase with increasing deposition time, while the asphaltene
content of the inner-layer wax deposit stays almost the same at deposition
time ≥ 1 h. The presence of asphaltenes greatly modifies the
precipitated wax crystals’ morphology (spherical-like flocs)
and then favors the diffusion of asphaltenes and wax molecules. Both
molecular diffusion of waxes and Brownian diffusion of asphaltenes
result in the formation of the two-layer wax deposit, which is formed
by a four-step process. The increase of the original asphaltene content
decreases the mass but increases the WAT and wax and asphaltene contents
of the inner-layer wax deposit.