The distributions of the thermal effects of the ion thruster plume are essential for estimating the influence of the thruster plume, improving the layout of the spacecraft, and the thermal shielding of critical sensitive components. In order to obtain the heat flow distribution in the plume of the LIPS-200 xenon ion thruster, an experimental study of the thermal effects of the plume was conducted in this work with a total heat flow sensor and a radiant heat flow sensor over an axial distance of 0.5–0.9 m and an angle of 0°–60° of the thruster. Combined with a Faraday probe and a retarding potential analyzer, the thermal accommodation coefficient of the sensor surface in the plume is available. The results of the experiment show that the xenon ion thruster plume heat flow is mainly concentrated within the range of 15°. The total and radial heat flow of the plume downstream of the thruster gradually decreases along the axial and radial directions, with the corresponding values of 11.78 kW/m2 and 0.3 kW/m2 for the axial 0.5 m position respectively. At the same position, the radiation heat flow accounts for a very small part of the total heat flow, approximately 3%–5%. The thermal accommodation factor is 0.72–0.99 over the measured region. Furthermore, the PIC and DSMC methods based on the Maxwell thermal accommodation coefficient model (EX-PWS) show a maximum error of 28.6% between simulation and experiment for LIPS-200 ion thruster plume heat flow, which on one hand provides an experimental basis for studying the interaction between the ion thruster and the spacecraft, on the other hand provides optimization of the ion thruster plume simulation model.