Since the 1930s, germicidal ultraviolet (GUV) irradiation
has been
used indoors to prevent the transmission of airborne diseases, such
as tuberculosis and measles. Recently, it has received renewed attention
due to the COVID-19 pandemic. While GUV radiation has been shown to
be effective in inactivating airborne bacteria and viruses, few studies
on the impact of GUV on indoor air quality have been published. In
this work, we evaluate the effects of GUV222 (GUV at 222 nm) on the
chemistry of a common indoor volatile organic compound (VOC), limonene.
We found that the production of O3 by the GUV222 lamps
caused the formation of particulate matter (PM) and oxygenated volatile
organic compounds (VOCs). We also found that the chemistry proceeds
through the ozonolysis of limonene as well as the reaction with secondary
OH, and that the presence of GUV light led to observable but small
perturbations to this chemistry. Understanding the effects of GUV222
on indoor air quality is important in evaluating the safety of these
devices.