Copper pipes used in fire sprinkler systems are somewhat superior to steel pipes in terms of corrosion resistance. They have been widely used in apartments since 2010, but their firefighting performance has not been firmly established due to leakage caused by pitting. In order to solve this problem, copper pipes need to be replaced by pipes made of other materials such as STS or C-PVC, which, however, would impose an economic burden on the party responsible for maintenance, as well as economic loss to other relevant parties and inconvenience to residents. Although 27 leakages occurred in the E region in 2018, it was found that the number of incidents was reduced to just one case after an application of corrosion inhibitor. Therefore, for 2 months beginning in October 2020, a second project to reduce piping corrosion was conducted with 2,000 households in five regions nationwide. During this period, the standing fire water of five apartment buildings in the A region was measured as having a pH 8.34–9.08, an ORP -94.9–-135.8 mV, and an EC 0.097–0.137 ms/cm, which indicated a need for improvement. Subsequently, a corrosion inhibitor was poured into the fire water, resulting in improved values of pH 11.13–11.26, ORP -257–-265.5 mV, and EC 4.189–5.769 ms/cm, which demonstrated the effect of preventing pipe corrosion. It was evident that water-soluble silicate was adsorbed on the metal pipe of the anode to form a thin monolayer, which induced basicity by increasing the pH and by decreasing the ORP, which eventually minimized corrosion.