Investigation the Corrosion Inhibition Effect of Itraconazole on Copper in H2SO4 at Different Temperatures: Combining Experimental and Theoretical Studies

Abstract

The anti-corrosion inhibition effect of itraconazole on copper (Cu) in 0.5 M H2SO4 is observed with variety of experimental methods, including electrochemical measurement, surface morphology analysis, and theoretical calculations. These experimental results all confirm that itraconazole exhibits excellent anti-corrosion performance in the certain temperatures range (298 K–313 K) for copper in sulfuric acid solution. In addition, corresponding adsorption isothermal models were used to fit the adsorption behavior of itraconazole on the copper surface. The results show that the Langmuir adsorption model agrees best with the experimental results. The adsorption of itraconazole on the copper surface belongs to chemical and physical adsorption.

Green inhibitor of carbon steel corrosion in 1 M hydrochloric acid:Eruca sativaseed extract (experimental and theoretical studies)

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Influence of 5-Chlorobenzotriazole on Inhibition of Copper Corrosion in Acid Rain Solution

“…Increasing values of E HOMO facilitate adsorption and therefore enhance the inhibition efficiency by influencing the transport process through the adsorbed layer . The low values of Δ E corresponds to a higher corrosion inhibition efficiency, also small value of η shows that it reacts with the surface more readily and the corrosion effect decreases, and on the other hand great μ facilitates interaction with the metal surface. Similar observations are already presented in the literature. , Parameter Δ N , also known as electron-donating ability, evaluates the tendency of a molecule to donate electrons to the metal surface, and the inhibition efficiency increases by increasing the electron-donating ability of the inhibitor to donate electrons to the metal …”

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