Investigations of a Diol‐based Sol‐Gel Process for the Preparation of Lead Titanate Materials

Abstract

Lead titanate sols were prepared by a sol-gel method from lead acetate trihydrate, Pb(OOCCH3),.3H,0, and titanium di-isopropoxide bis-acetylacetonate, Ti (OC,H,),-(CH,COCHCOCH,),, in 1,3-propanediol, HO(CH,),OH, as solvent. IR analysis and NMR spectroscopic techniques were used to study the reaction mechanisms and to identify possible polymer structures developed during synthesis of the solutions.

Enhanced sunlight-driven photocatalytic activity of graphene oxide/Bi2WO6 nanoplates by silicon modification

“…As shown in Fig. 2, the main absorption bands in the range of 400-1000 cm À 1 are attributed to the responses of Bi-O, W-O and W-O-W stretching modes in Bi 2 WO 6 crystal [24,25]. The band at 1100 cm À 1 is assigned to the Si-O vibration in silicates [26], further confirming the existence of Bi 12 SiO 20 .…”

Structural studies of TEOS-tetraethoxytitanate based hybrids

“…2. This effect is due to thermal decomposition and burning of -OCH 3 groups [3,4]. This process is shifted into the higher temperature $500°C when the GLYMO content increase.…”

Dielectric properties of sol–gel derived CaCu3Ti4O12 thin films onto Pt/TiO2/Si(100) substrates

“…A titanium diol-based sol was prepared 14 COOH] were prepared by stirring the acetates in the acid. Molar ratios of any of the acetates to the acid of 1/10 were used.…”