“…In this context, time resolved (where temperature and pressure are kept constant during the experiment), temperature resolved (where the number of probe molecules in the cell is kept constant while changing the temperature) and pressure resolved (where temperature is fixed, while pressure is changing by acting on the number of probe molecules in the cell) FT-IR spectroscopy represents an useful tool for characterization purposes and for kinetic studies concerning several kind of reactions [10]. However, notwithstanding the fact that commercial cryostats able to reach liquid helium temperatures were available since decades and widely employed in the field of solid state physics [11][12][13][14][15], the lower temperature value at which experiments were performed was limited for a long period to 77 K, mainly due to practical problems. This was mainly due to the www.elsevier.com/locate/cattod Catalysis Today 113 (2006) [65][66][67][68][69][70][71][72][73][74][75][76][77][78][79][80] incompatibility of the materials used to reach and confine very low temperatures with the high temperatures usually needed to activate the surfaces of catalysts, that has prevented for long time the overcoming of the 77 K barrier in FT-IR experiments of species adsorbed on active surface sites.…”