IntroductionDuring the late 20th century, the growing interest in creating advanced materials using nanoscaled building blocks was employed to develop synthetic techniques for re-engineering existing materials to novel functional materials such as quantum dots, nanodots, nanorods, nanotubes, nanofibrils and quantum wires. These nanowires can act as one-dimensional conductors with interesting electronic and optical properties. Moreover, nanowires may find applications in ultrasensitive chemical and biological sensors.To date, a physical vapor deposition (PVD) technique followed by lithography is usually considered to represent the ultimate method for producing nanoscaled materials. Although a number of successful efforts have been reported on the fabrication of freestanding nanopillars or nanowells using lithographic techniques, there is a whole range of potential obstacles for these approaches. These arise mainly from the fact that, when the technologies are pushed to smaller sizes, the cost rapidly escalate and the tolerances are more difficult to maintain. The lithographic processes used to pattern nanoelectronic structures also currently limit the dimensions of the electronic components such as nanowires. Optical lithography is limited by the wavelength of the light used to produce the wires. Consequently, the wavelength of light used is moving into the deeper regions of the ultraviolet (UV) spectrum, and the cost of fabricating optical components to achieve this is expected to rise at an astronomic rate. These challenges have forced many to seek new nanofabrication techniques, especially those which grow nanostructures directly in the openings of a template. One of the most successful approaches to these nanofabrication methods is known as the membrane-based synthesis of nanomaterials [1][2][3][4], where the membrane acts as a template for the electrodeposition of multilayered nanowires, as well as for single metallic nanowires [5,6]. The advantage of using template synthesis of nanowires is that it can be considered as an alternative solution to overcome the difficulty in fabricating fibrils with very small diameters by lithographic methods [7].