1986
DOI: 10.1021/ma00165a036
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Ionic aggregation in model ionomers

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Cited by 122 publications
(120 citation statements)
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“…Changing the proton into a heavier cation is not supposed to alter the essential details of the structure because the cations appear to have minor role in that respect. 1,8 …”
Section: Introductionmentioning
confidence: 99%
“…Changing the proton into a heavier cation is not supposed to alter the essential details of the structure because the cations appear to have minor role in that respect. 1,8 …”
Section: Introductionmentioning
confidence: 99%
“…Several years ago, a new type of linear polymer [22,23] selectively end-capped with an ionic group at both ends was synthesized and referred to as halato-telechelic polymers (HTPs). They are model compounds for the more complex ionomers that have been thoroughly studied in the solid state [24][25][26][27] and in solution [28 30]. HTPs are self-associating compounds in apolar solvents and a sol-gel transition is currently observed at very low polymer concentrations.…”
Section: Introductionmentioning
confidence: 99%
“…The weak dependence of n ag on the type of counterion con®rms the results from SAXS on sulfonated PS. 16 For sulfonated PS with M w = 3 kg mol À1 , Vanhoorne and co-workers 4,5 observed no dependence for monovalent ions, but a decrease with increasing radius of divalent ions.…”
Section: In¯uence Of the Molar Massmentioning
confidence: 97%