Ionic hydrogenation of acyl derivatives of cyclopentadienylmanganese tricarbonyl

Kursanov, D. N.; Anisimov, K. N.; Parnes, Z. P.; Loim, N. M.; Zlotina, I. B.; Valueva, Z. P.

doi:10.1007/bf00863253

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Reduction Of Aldehydes1

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2009

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Cited by 7 publications

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“…Since the organosilane reduction of benzyl alcohols to the corresponding toluene derivatives is known, it is not surprising that the reduction of an aryl aldehyde to a toluene is possible. This transformation has been carried out with Et 3 SiH/TFA, 69,351,352 (EtO) 3 SiH, and Et 3 SiH with various catalysts, 353 Et 3 SiH/(C 6 F 5 ) 3 B, 281 PMHS/Pd/C, 316 and PMHS/ (C 6 F 5 ) 3 B. 354 The last combination also reduces alkyl aldehydes to the corresponding alkanes (Eq.…”

Section: Reduction Of Aldehydesmentioning

confidence: 99%

Ionic and Organometallic‐Catalyzed Organosilane Reductions

2009

Ionic and Organometallic‐Catalyzed Organosilane Reductions

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Section: Reduction Of Aldehydesmentioning

confidence: 99%

Ionic and Organometallic‐Catalyzed Organosilane Reductions

2009

Ionic and Organometallic‐Catalyzed Organosilane Reductions

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Ionic and Organometallic‐Catalyzed Organosilane Reductions

Larson

Fry²

2008

Organic Reactions

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This chapter presents a critical review of synthetically useful variations of ionic methods for hydrogenation of organic compounds. In practice ionic hydrogenation involves the formal introduction of hydride from a donor source to an electron‐deficient carbon center. In this chapter, organosilicon hydrides are used as the source of ionic hydride with the goal of completing and updating earlier review work. Organosilicon compounds with at least one Si‐H bond have the ability to serve as mild‐air and water‐stable sources of hydrides and, thus, have reducing properties. In general, organosilicon hydrides do not undergo spontaneous reactions with organic compounds unless the organic substrate is a reasonably strong electrophile or the silane is first activated by the interaction of a nucleophilic species with a nucleophilic center. The organosilicon hydrides are covalent compounds that have little or no nucleophilic properties on their own. The use of these hydrides often provides a means of effecting reductions of organic substrates under very mild conditions and with excellent functional group selectivity. Consideration of the nature of the Si‐H bonds provides insight into the chemical behavior of these hydrides. Enhanced hydridic nature manifests itself in the chemical behavior of hydrosilanes.

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Ionic and Organometallic‐Catalyzed Organosilane Reductions

Larson

Fry²

2009

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Ionic hydrogenation of acyl derivatives of cyclopentadienylmanganese tricarbonyl

Cited by 7 publications

References 3 publications

Ionic and Organometallic‐Catalyzed Organosilane Reductions

Ionic and Organometallic‐Catalyzed Organosilane Reductions

Ionic and Organometallic‐Catalyzed Organosilane Reductions

Ionic and Organometallic‐Catalyzed Organosilane Reductions

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