Abstract-Electron and hole ionization coefficients inIn 0 53 Ga 0 47 As are deduced from mixed carrier avalanche photomultiplication measurements on a series of p-i-n diode layers, eliminating other effects that can lead to an increase in photocurrent with reverse bias. Low field ionization is observed for electrons but not for holes, resulting in a larger ratio of ionization coefficients, even at moderately high electric fields than previously reported. The measured ionization coefficients are marginally lower than those of GaAs for fields above 250 kVcm 1 , supporting reports of slightly higher avalanche breakdown voltages in In 0 53 Ga 0 47 As than in GaAs p-i-n diodes.