Ionization of O3 in Excess N2: A New Route to N2O via Intermediate N2O3+ Complexes

Recent mass spectrometric studies of species and processes relevant to the chemistry of atmospheres are reported. New species have been detected, including HO(3); a stratospheric reservoir of OH radicals; the [H(2)O(+)O(2)(-)] charge transfer complex, central to the atmospheric photonucleation theory; and the OSOSO oxide and its cation, likely present in the Io's atmosphere. As to ionic processes, a new route to tropospheric N(2)O in air ionized by lightning and coronas is reported, as well as the complex chemistry promoted by ionization of ozone/freon and ozone/carbonyl sulfide mixtures and the formation of O(5)(+), relevant to the problem of (18)O excess in stratospheric ozone.

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Ionization of O3 in Excess N2: A New Route to N2O via Intermediate N2O3+ Complexes

Cited by 4 publications

References 35 publications

The influence of O4 in Chapman's model for stratospheric ozone

The influence of O4 in Chapman's model for stratospheric ozone

Discovery and characterization of atmospherically relevant inorganic species by structurally diagnostic mass spectrometric techniques

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