2015
DOI: 10.1007/3418_2015_101
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Iron-Catalyzed Oligomerization and Polymerization Reactions

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Cited by 30 publications
(19 citation statements)
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“…Research in the area of iron-catalyzed polymerization reactions was significantly advanced when Gibson [27] and Brookhart [26] found independently that 2,6-bis(arylimino)pyridyl iron(II) complexes (5 in Fig. 2) catalyze the oligomerization and polymerization of ethylene, as further described by Hélène OlivierBourbigou in [28]. As can be seen in Fig.…”
Section: Polymerization Reactionsmentioning
confidence: 91%
See 1 more Smart Citation
“…Research in the area of iron-catalyzed polymerization reactions was significantly advanced when Gibson [27] and Brookhart [26] found independently that 2,6-bis(arylimino)pyridyl iron(II) complexes (5 in Fig. 2) catalyze the oligomerization and polymerization of ethylene, as further described by Hélène OlivierBourbigou in [28]. As can be seen in Fig.…”
Section: Polymerization Reactionsmentioning
confidence: 91%
“…In the late 1990s, Brookhart [26] and Gibson [27] discovered that bis(imino)pyridyl iron complexes were efficient catalysts for ethylene polymerization reactions, which initiated vigorous research activities in the field. Polymerization reactions are further discussed by Hélène Olivier-Bourbigou in [28]. The field of iron-catalyzed cross-coupling reactions -based on Vavon's early work in the 1940s and Kochi's findings in the early 1970s -was revitalized in the early 2000s, as described by Robin Bedford in [29].…”
Section: Historic Developmentmentioning
confidence: 97%
“…Based on the growing experimental and computational data, the non-innocence of the bis(arylimino)pyridine ligand has been demonstrated [7][8][9][10][11][12][13][14][15]. Recently, Bryliakov and…”
Section: The Active Iron Speciesmentioning
confidence: 99%
“…Over recent years there have been some notable advances in the development of well-defined homogeneous catalysts based on earth-abundant base metals [1][2][3][4][5][6][7][8][9][10][11][12]. In particular, iron and cobalt complexes supported by pincer ligands have been shown to promote a wide variety of important transformations including, (i) the hydrogenation of olefins, carbonyl compounds, carboxylic acid derivatives and CO2 [13][14][15][16][17][18][19][20][21][22][23][24][25][26][27][28][29], (ii) the dehydrogenation of alcohols, amines and alkanes [30][31][32][33][34][35], (iii) transfer hydrogenation reactions [36] and (iv) dehydrogenative cross-coupling [37][38][39].…”
Section: Introductionmentioning
confidence: 99%
“…Over the past two decades ago, Brookhart [1,2] and Gibson [3,4,5] independently discovered the well-defined bis(imino)pyridine-cobalt and -iron complexes ( A ) as highly active precatalysts for ethylene oligo-/polymerization. In the intervening years, large numbers of different skeletal modifications, such as changes to the N -aryl groups and the backbone of pyridine, have been made to the bis(imino)pyridine scaffolds ( A , Chart 1) [6,7,8,9,10,11,12,13,14,15], culminating in improvements to both catalytic activity and thermal stability [6,16,17,18,19,20,21,22,23,24,25,26,27,28,29,30,31,32,33]. The related progress was collected in several reviews [6,9,10,11,14,15].…”
Section: Introductionmentioning
confidence: 99%