Irreversible exchange of potassium with thallium in coordination polymer nanostructures upon solid-state Mechanochemical process

Mirzadeh, Elham; Akhbari, Kamran; White, Jonathan M.

doi:10.1016/j.inoche.2018.04.010

Cited by 7 publications

(1 citation statement)

References 34 publications

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“…Solid‐state reactions by manual or mechanical grinding with least or solvent free for molecular synthesis have triggered lots of attention . Mechanochemical synthesis corresponds to chemical reactivity achieved by mechanical force . To advance solid‐state reactions, mechanochemical methods such as grinding with a pestle and mortar have been found to be impressive .…”

Section: Introductionmentioning

confidence: 99%

Green conversion of a three‐dimensional organometallic coordination polymer to a three‐dimensional organometallic supramolecular polymer upon mechanochemical 2‐aminopyridine addition

Usefi

Akhbari

Phuruangrat

2019

Applied Organom Chemis

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Green conversion of three‐dimensional organometallic [Ag2(μ6‐tp)]n (1) coordination polymer (CP) nanosheets, prepared by sonochemical procedure, to three‐dimensional organometallic [Ag2(μ4‐tp)(apy)2]n (2) (where H2tp = terephthalic acid and apy = 2‐aminopyridine) CP nanoparticles has been observed upon solid‐state mechanochemical reaction of compound 1 with 2‐aminopyridine. The AgO3Ag···C6 coordination sphere of silver ion in 1 changed to NO2Ag···C coordination sphere in 2 during this mechanochemical addition. These samples were characterized by infrared spectroscopy, thermogravimetric and differential thermal analyses, X‐ray powder diffraction and scanning electron microscopy.

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Section: Introductionmentioning

confidence: 99%