2012
DOI: 10.1002/ejic.201101326
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Isolation of a New Cs‐Symmetrized Mo33‐S)(μ‐S)(μ‐S2)2 Structural Type Through Complementary Association with a Cubane‐Type Mo3NiS4 Cluster

Abstract: Registro de acceso restringido Este recurso no está disponible en acceso abierto por política de la editorial. No obstante, se puede acceder al texto completo desde la Universitat Jaume I o si el usuario cuenta con suscripción. Registre d'accés restringit Aquest recurs no està disponible en accés obert per política de l'editorial. No obstant això, es pot accedir al text complet des de la Universitat Jaume I o si l'usuari compta amb subscripció. Restricted access item This item isn't open access because of publ… Show more

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Cited by 3 publications
(1 citation statement)
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“…[30][31][32] This arrangement inherently furnishes chirality to the core, 33,34 and differs from a second coordination arrangement where both donors occupy trans-to-μ-S positions as shown in Scheme 1c in the case of acetylacetonato ligands. [35][36][37] Complexes with an arrangement of the type [Mo 3 S 4 -(η 2 -dtp) 3 L 3 ] + (Scheme 1a; L = neutral N-donor) can readily be prepared, 26,38 very often as [Mo 3 S 4 (η 2 -dtp) 3 (η 2 (μ)-E-E)(L)] (n−1)+ (n being the charge of the E-E ligand) derivatives (Scheme 1b). In these compounds the E-E bridging ligand (a carboxylate anion in most cases) locks two of the three monodentate neutral donor positions, [39][40][41] thus leaving a single metal coordination site amenable to coordination of L ligands.…”
Section: Introductionmentioning
confidence: 99%
“…[30][31][32] This arrangement inherently furnishes chirality to the core, 33,34 and differs from a second coordination arrangement where both donors occupy trans-to-μ-S positions as shown in Scheme 1c in the case of acetylacetonato ligands. [35][36][37] Complexes with an arrangement of the type [Mo 3 S 4 -(η 2 -dtp) 3 L 3 ] + (Scheme 1a; L = neutral N-donor) can readily be prepared, 26,38 very often as [Mo 3 S 4 (η 2 -dtp) 3 (η 2 (μ)-E-E)(L)] (n−1)+ (n being the charge of the E-E ligand) derivatives (Scheme 1b). In these compounds the E-E bridging ligand (a carboxylate anion in most cases) locks two of the three monodentate neutral donor positions, [39][40][41] thus leaving a single metal coordination site amenable to coordination of L ligands.…”
Section: Introductionmentioning
confidence: 99%