Isomerization

Perry, Stephen F.

doi:10.1021/ie50513a027

Cited by 2 publications

(1 citation statement)

References 15 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Widespread in nature − and key to many industrial applications, − isomerization reactions have been extensively studied in chemistry and physics, both experimentally and theoretically. , The C 2 H 2 molecule in particular has proven to be a useful testing ground for examining isomerization. Conversion between its acetylene (HCCH) and vinylidene (H 2 CC) isomers, an example of 1,2 hydrogen migration, is one of the simplest bond rearrangement isomerization reactions.…”

mentioning

confidence: 99%

Dependence on the Initial Configuration of Strong Field-Driven Isomerization of C₂H₂ Cations and Anions

Jochim

Berry

Severt

et al. 2019

J. Phys. Chem. Lett.

View full text Add to dashboard Cite

We have investigated the femtosecond laser-induced fragmentation of C2H2 q ion beam targets in various initial configurations, including acetylene (linear HCCH), vinylidene (H2CC), and cis/trans. The initial configuration is shown to have a tremendous impact on the branching ratio of acetylene-like (CH q 1 + CH q 2 ) and vinylidene-like (C q 1′ + CH2 q 2′) dissociation of a specific C2H2 q molecular ion. In particular, whereas C2H2 + generated from C2H2, a linear HCCH target, exhibits comparable levels of acetylene-like and vinylidene-like fragmentation, vinylidene or cis/trans configuration ion beams preferably undergo vinylidene-like fragmentation, with an acetylene branching ratio ranging from 13.9% to zero.

show abstract

mentioning

confidence: 99%

Dependence on the Initial Configuration of Strong Field-Driven Isomerization of C₂H₂ Cations and Anions

Jochim

Berry

Severt

et al. 2019

J. Phys. Chem. Lett.

View full text Add to dashboard Cite

show abstract

Das Polymerisieren, Alkylieren und Isomerisieren

Riediger¹

1971

Die Verarbeitung Des Erdöles

View full text Add to dashboard Cite

Isomerization

Cited by 2 publications

References 15 publications

Dependence on the Initial Configuration of Strong Field-Driven Isomerization of C₂H₂ Cations and Anions

Dependence on the Initial Configuration of Strong Field-Driven Isomerization of C₂H₂ Cations and Anions

Das Polymerisieren, Alkylieren und Isomerisieren

Contact Info

Product

Resources

About

Isomerization

Cited by 2 publications

References 15 publications

Dependence on the Initial Configuration of Strong Field-Driven Isomerization of C2H2 Cations and Anions

Dependence on the Initial Configuration of Strong Field-Driven Isomerization of C2H2 Cations and Anions

Das Polymerisieren, Alkylieren und Isomerisieren

Contact Info

Product

Resources

About

Dependence on the Initial Configuration of Strong Field-Driven Isomerization of C₂H₂ Cations and Anions

Dependence on the Initial Configuration of Strong Field-Driven Isomerization of C₂H₂ Cations and Anions