Jet-Cooled Optical Spectroscopy of FeN between 16 300 and 21 600 cm−1

Aiuchi, Kosuke; Shibuya, Kazuhiko

doi:10.1006/jmsp.2000.8226

Cited by 15 publications

(22 citation statements)

References 34 publications

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“…The F 2 + state is affected by interactions from a closelying 2 state as has been observed for the E 2 + state of RhC (20). The ground state equilibrium bond length of r e = 1.5714Å for RuN is similar to the values of r 0 = 1.580Å for FeN (11) and r e = 1.6180Å for OsN (13).…”

Section: Resultssupporting

confidence: 56%

“…The equilibrium ground state bond length of r e = 1.5714269(60)Å compares well with the predicted value of r e = 1.578Å from the previous ab initio calculation (12). This value can also be compared with the values of r e = 1.716Å for RuO (31), r e = 1.613Å for RhC (19), r 0 = 1.581Å for FeN (11), and r e = 1.618Å OsN (13). The short bond length of RuN compared to that of RuO is consistent with a formal triple bond between the atoms.…”

Section: Discussionmentioning

confidence: 61%

“…In an extensive study, Aiuchi and Shibuya (11) generated FeN in the reaction of laser-ablated Fe atoms with NH 3 using a supersonic jet expansion source and analyzed a number of bands. The ground state of FeN has been identified as the = 5/2 spin component of a 2 i state (11). RuN (12) and OsN (13) have also been investigated recently at high resolution and ground states of 2 + and 2 i symmetry (respectively) have been estab-lished.…”

Section: Introductionmentioning

confidence: 99%

“…For the group 8 transition metal family, in particular, high-resolution spectroscopic data are now available for FeN (11), RuN (12), and OsN (13). In an extensive study, Aiuchi and Shibuya (11) generated FeN in the reaction of laser-ablated Fe atoms with NH 3 using a supersonic jet expansion source and analyzed a number of bands.…”

Section: Introductionmentioning

confidence: 99%

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Fourier Transform Emission Spectroscopy of the F2Σ+–X2Σ+ System of RuN

Ram

Bernath

2002

Journal of Molecular Spectroscopy

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Section: Resultssupporting

confidence: 56%

Section: Discussionmentioning

confidence: 61%

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

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Fourier Transform Emission Spectroscopy of the F2Σ+–X2Σ+ System of RuN

Ram

Bernath

2002

Journal of Molecular Spectroscopy

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“…The spectrum shows many perturbations, as has been seen in many of the diatomic transition metal monoxides, mononitrides, and monocarbides. However, the identification of the band systems is relatively straightforward using isotope shifts and vibrational spacings, particularly as compared with FeN, for which the vibronic structure in the visible region was found to be almost chaotic in our recent work (21).…”

Section: Resultsmentioning

confidence: 98%

The Electronic Spectrum of Jet-Cooled FeC in the Visible Region

Aiuchi

Shibuya

2001

Journal of Molecular Spectroscopy

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Metal–Ligand Multiple Bonds

Crabtree

2005

The Organometallic Chemistry of the Transition Metals

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Throughout the writing of this dissertation I have received a great deal of support and assistance. I would first like to thank my supervisor, Prof. Dr. Sebastian Hasenstab-Riedel, for the opportunity to conduct my doctoral thesis in his group, for the interesting topic, for his support, and for his encouraging enthusiasm. Next, I would like to thank Prof. Dr. Martin Kaupp for his time and effort to assess my work as a second referee. Thanks also to the other members of my committee for their time and effort. I would like to express my sincere gratitude to Dr. habil. Helmut Beckers for proofreading all my manuscripts and whose office door was always open whenever I ran into a trouble spot or had a question about my research or writing. His patience during our countless discussions and insight have steered me through this work. Thanks to Thomas Hohmann and Xia Xiya for their help while working under my supervision for their internship and Bachelor thesis, respectively. Many thanks go to the entire working group for the very pleasant working atmosphere, for the many productive discussions and the general helpfulness of everyone. I will especially have fond memories of my colleagues and friends Dr. Li Lin and Dr. Frenio Redeker from the matrix-isolation subgroup. Finally, I must express my gratitude to my beloved partner Dr. Rita Fernandes, who provided me with unfailing support, proofread this work and the continuous encouragement throughout my years of study. My appreciation also goes out to my dear parents Monika and Gert Stüker, and my dear brother Martin Stüker for their encouragement and support. This accomplishment would not have been possible without them.iii Metal-Ligand Multiple Bonds Nitrido and Fluoroimido Complexes of High-Valent Late Transition Metals

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Jet-Cooled Optical Spectroscopy of FeN between 16 300 and 21 600 cm−1

Cited by 15 publications

References 34 publications

Fourier Transform Emission Spectroscopy of the F2Σ+–X2Σ+ System of RuN

Fourier Transform Emission Spectroscopy of the F2Σ+–X2Σ+ System of RuN

The Electronic Spectrum of Jet-Cooled FeC in the Visible Region

Metal–Ligand Multiple Bonds

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