New nanocomposites based on zeolites (NaA-NaNO 2 , NaA-NaNO 3 ) and opals (o-NaNO 2 , o-NaNO 3 ) that contain sodium nitrite or sodium nitrate nanoparticles in cages of regular porous matrices are prepared. The nanocomposites are characterized by scanning electron microscopy, diffuse reflectance spectroscopy, and electrical measurements.