Dual‐ion batteries have been considered as a competitive energy storage device. However, owing to the lack of the suitable high‐capacity density and rapid‐charging kinetics electrode materials, designing a cost‐effective and high performance dual‐ion battery is still a great challenge. Herein, an ultrahigh‐capacity dual‐ion battery is constructed based on the SnS2‐MoS2@CNTs heterojunction anode and high crystallinity free‐standing graphite paper serves as cathode. The SnS2‐MoS2@CNTs heterojunction consisted of ultrathin nanosheets is prepared via a facile two‐step hydrothermal method, and shows flower‐like morphology and high crystallinity. Benefiting from the unique design concept, the Graphite paper/SnS2‐MoS2@CNTs dual‐ion battery delivers a high capacity of 274.2 mA h g‐1 at 100 mA g‐1 and keeps an outstanding capacity retention of 95% after 300 cycles under 400 mA g‐1. Even at a high current density of 2 A g‐1, the battery still retains a considerable capacity of 112.3 mA h g‐1. More importantly, the battery shows an extremely low self‐discharge of 0.006% h‐1 after resting for 24 h. The characterization of SEM and XRD further demonstrate the excellent cycling stability and good reversibility. Consequently, this constructed dual‐ion battery could be a promising energy storage device and provide new insight for the design of high‐performance dual‐ion batteries.