wearable devices, [1,2] sensitive robotic skin, [3] electronic papers, [4] soft surgical tools, [5] electronic imaging devices, [5] in vivo health monitors, [3] as well as various collapsible gadgets [6] has attracted widespread attention upon flexible and stretchable electronics with a combination of advanced electrical performance with robust mechanical properties such as stretchability, foldability, twistability, flexibility, and durability. [7,8] In particular, device stretchability is highly desirable for wearable electronics due to the inevitable deformation (strain) generated in human skin and human body activity. As essential components of stretchable electronics systems, energy conversion and storage devices should be capable of sustaining their performance when subjected to the large strains that may be experienced by the highly stretchable electronics in various applications. The consistency of stretchability in both electronics and energy devices becomes the key to the successful integration of a combined self-powered stretchable system in wearable electronics applications. To date, significant effort and progress have been made in developing stretchable energy devices such as batteries, supercapacitors (SCs), and solar cells. [9][10][11][12][13] Although batteries are typically favored among power sources for electronic devices due to their superior power density and energy Supercapacitors (SCs) have shown great potential for mobile energy storage technology owing to their long-term durability, electrochemical stability, structural simplicity, as well as exceptional power density without much compromise in the energy density and cycle life parameters. As a result, stretchable SC devices have been incorporated in a variety of emerging electronics applications ranging from wearable electronic textiles to microrobots to integrated energy systems. In this review, the recent progress and achievements in the field of stretchable SCs enabled by low-dimensional nanomaterials such as polypyrrole, carbon nanotubes, and graphene are presented. First, the three major categories of stretchable supercapacitors are discussed: double-layer supercapacitors, pseudo-supercapacitors, and hybrid supercapacitors. Then, the representative progress in developing stretchable electrodes with low-dimensional (0D, 1D, and 2D) nanomaterials is described. Next, the design strategies enabling the stretchability of the devices, including the wavy-shape design, wire-shape design, textile-shape design, kirigami-shape design, origami-shape design, and serpentine bridgeisland design are emphasized, with the aim of improving the electrochemical performance under the complex stretchability conditions that may be encountered in practical applications. Finally, the newest developments, major challenges, and outlook in the field of stretchable SC development and manufacturing are discussed.
Stretchable SupercapacitorsThe ORCID identification number(s) for the author(s) of this article can be found under https://doi.