Kinetic parameters of unsaturated polyester resin modified with poly(ε -caprolactone)

Escribano, José M.; Masegosa, Rosa M.; Nava, D.; Prolongo, M. G.; Salom, C.

doi:10.1007/s10973-006-7892-8

Cited by 5 publications

(1 citation statement)

References 22 publications

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“…where t is the time, T the temperature, k is the rate constant and f (α) is a function of degree of conversion. Assuming that the curing reaction follows n th order kinetics f (α) has the form [ 25 ]: f (α) = (1 – α ) n . Substituting f (α) in Equation ( 9 ) and applying logarithmic, the equation can be written as; …”

Section: Methodsmentioning

confidence: 99%

Designing of cardanol based polyol and its curing kinetics with melamine formaldehyde resin

Balgude

Sabnis

Ghosh³

2016

Designed Monomers and Polymers

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Commercially used industrial baking enamels consist of alkyd or polyester resin with melamine formaldehyde. These resins are mainly derived from fossil resources. Considering growing environmental legislation regarding use of petroleum based raw materials, utilization of renewable resources to synthesize various chemistries can be the only obvious option as far as academia and industries are concerns. The present work deals with exploration of one of the natural resources (Cardanol) for polyol synthesis, its characterization (FTIR and NMR) and its curing behavior with melamine formaldehyde resin by differential scanning calorimetry (DSC). The optimized formulations from DSC study were further evaluated for general coating properties to study the suitability of developed polyol for industrial coating application. The experimental studies revealed that melamine content in the curing mixtures and thereby developed crosslinking density played an important role in deciding the coatings properties.

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Section: Methodsmentioning

confidence: 99%