Kinetic study of oxidation of cyclohexanol using bimetallic iron–copper macrocyclic complex catalyst

Jhansi, M.; Kishore, Lalit; Anand, K.; Kumar, Anil

doi:10.1016/j.catcom.2008.09.005

Cited by 11 publications

(4 citation statements)

References 21 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…In the conventional two-step process, phenol is firstly hydrogenated to cyclohexanol, and cyclohexanol is subsequently dehydrogenated to yield cyclohexanone. [13][14][15][16] Therefore, the one-step process, the selective hydrogenation of phenol to cyclohexanone, has a large number of advantages. It simplifies the reaction steps, improves the efficiency of the hydrogen utilization, reduces waste disposal, 3,[17][18][19] and avoids the difficult separation of phenol-cyclohexanol and phenolcyclohexanone azeotropes.…”

Section: Introductionmentioning

confidence: 99%

Selective hydrogenation of phenol and related derivatives

Zhong

Chen

2014

Catal. Sci. Technol.

117

View full text Add to dashboard Cite

show abstract

Section: Introductionmentioning

confidence: 99%

Selective hydrogenation of phenol and related derivatives

Zhong

Chen

2014

Catal. Sci. Technol.

117

View full text Add to dashboard Cite

show abstract

“…1d, the Pd presents a doublet corresponding to Pd 3d 5/2 and Pd 3d 3/2 . The Pd 3d 3/2 peak at 340.8 eV and the Pd 3d 5/2 peak at 335.6 eV are attributed to Pd 0 , while the peaks at 337.5 eV (Pd 3d 3/2 ) and 342.5 eV (Pd 3d 5/2 ) can be assigned to Pd + 2 .…”

Section: Resultsmentioning

confidence: 98%

“…Generally, phenol can be hydrogenation to cyclohexanone in a “one-step” or a “two-step” process. In two-step, phenol is hydrogenated to cyclohexanol firstly and cyclohexanol is dehydrogenated to yield cyclohexanone subsequently 2, 3 . The one-step process avoids the endothermic step of dehydrogenation and therefore is certainly preferable in terms of capital costs and energy savings.…”

Section: Introductionmentioning

confidence: 99%

Novel nano-semiconductor film layer supported nano-Pd Complex Nanostructured Catalyst Pd/Ⓕ-MeOx/AC for High Efficient Selective Hydrogenation of Phenol to Cyclohexanone

Ouyang

Zhang

et al. 2017

Sci Rep

View full text Add to dashboard Cite

Supported metal as a type of heterogeneous catalysts are the most widely used in industrial processes. High dispersion of the metal particles of supported catalyst is a key factor in determining the performance of such catalysts. Here we report a novel catalyst Pd/Ⓕ-MeOx/AC with complex nanostructured, Pd nanoparticles supported on the platelike nano-semiconductor film/activated carbon, prepared by the photocatalytic reduction method, which exhibited high efficient catalytic performance for selective hydrogenation of phenol to cyclohexanone. Conversion of phenol achieved up to more than 99% with a lower mole ratio (0.5%) of active components Pd and phenol within 2 h at 70 °C. The synergistic effect of metal nanoparticles and nano-semiconductors support layer and the greatly increasing of contact interface of nano-metal-semiconductors may be responsible for the high efficiency. This work provides a clear demonstration that complex nanostructured catalysts with nano-metal and nano-semiconductor film layer supported on high specific surface AC can yield enhanced catalytic activity and can afford promising approach for developing new supported catalyst.

show abstract

“…Oxidation of alcohols to the corresponding ketones and aldehydes is a key reaction in organic synthesis [20][21][22], since the selective formation of carbonyl functional groups in hydrocarbons makes them useful intermediaries for pharmaceuticals and cosmetic products [23]. Cr-containing catalysts have found application on the oxidation of several organic substrates, including cyclohexene and cyclohexanol [24][25][26].…”

Section: Introductionmentioning

confidence: 99%