2008
DOI: 10.1016/j.foodchem.2008.05.033
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Kinetic study on the Maillard reaction. Consideration of sugar reactivity

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Cited by 212 publications
(154 citation statements)
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“…As shown in Table 1a and Figure 3b at 294 nm, the AUC of glycoconjugates obtained with xylose in HX0.6 and HX1.2 were higher than that of HN by factors of ~11.5 and ~27.4, respectively. This reflects the production of aromatic intermediates of the MR and is in accordance with results obtained using high reactive sugars such as pentoses (Laroque et al, 2008). Figure 3c and 3d show that glycoconjugates with dextran exhibited chromatographic patterns quite similar to those with native protein sources (CN and HN).…”
Section: Molecular Weight Size Distribution Of Mr Productssupporting
confidence: 86%
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“…As shown in Table 1a and Figure 3b at 294 nm, the AUC of glycoconjugates obtained with xylose in HX0.6 and HX1.2 were higher than that of HN by factors of ~11.5 and ~27.4, respectively. This reflects the production of aromatic intermediates of the MR and is in accordance with results obtained using high reactive sugars such as pentoses (Laroque et al, 2008). Figure 3c and 3d show that glycoconjugates with dextran exhibited chromatographic patterns quite similar to those with native protein sources (CN and HN).…”
Section: Molecular Weight Size Distribution Of Mr Productssupporting
confidence: 86%
“…We have previously showed that pentoses are more reactive than hexoses due to the higher proportion of their acyclic form, which ultimately condition the sugar reactivity in MR (Laroque et al, 2008). Polysaccharides can be also used to produce MRPs (Evans et al, 2013).…”
Section: Emulsifying and Antioxidant Properties Of A Shrimp (Pandalusmentioning
confidence: 99%
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“…Em adição à abundância das formas em cadeia aberta, outros fatores que influenciam a susceptibilidade à reação incluem o comprimento da cadeia do açúcar e a reatividade dos seus grupos funcionais, sendo as aldoses mais eletrofílicas que as cetoses e, portanto, mais reativas. 5,15 A formação dos AGEs envolve complexas reações sequenciais e paralelas e embora alguns dos seus mecanismos precisos sejam ainda objeto de investigações e debates, duas das suas principais vias são consideradas bem estabelecidas. São elas: (1) rearranjos irreversíveis dos produtos de Amadori seguidos de reações oxidativas ou não e (2) a condensação entre cadeias laterais dos resíduos de lisina, cisteína e arginina e produtos carbonílicos gerados desde os estágios iniciais da reação de Maillard.…”
Section: A Reação De Maillard E Os Mecanismos De Formação Dos Produtounclassified
“…In general, pentose sugars are more reactive than hexose sugars. Ketoses (fructose) are more reactive than aldoses (glucose) because of a high proportion of open chain forms in the Maillard reaction (Laroque et al 2008). Moreover, caramelization is more likely to occur from ketoses than from aldoses (Ajandouz et al 2001).…”
Section: Introductionmentioning
confidence: 99%