1981
DOI: 10.1021/es00090a004
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Kinetics and mechanism of ethanolamine chlorination

Abstract: Supplementary Material Available: Calculated vs. Experimental ozone values for Pitts et al. smog-chamber study on Los Angeles basin surrogate compositions (4 pages) will appear following these pages in the microfilm edition of this volume of the journal. Photocopies of the supplementary material from this paper on microfiche (105 X 148 mm, 24X reduction, negatives) may be obtained from Business Operations, Books and Journals Division, American Chemical Society, 1155 16th St., N.W., Washington, DC 20036. Full … Show more

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Cited by 10 publications
(3 citation statements)
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“…From the experimental data the rate constant k3 ( k H O C I ) for molecular mechanism (reaction 7) of each amine can be calculated, the logarithm of which shows a linear relationship with the pK2 of the amine, as shown in Figure 5 (4); EA (5); nPA (6); isoPA (7); p-alanine (8); alanine (9); glycine (10); 2-amino-2-(hydroxymethyl)-1,3propandiol (11); and glycylglycine (12). and analogous equations were obtained by using kg (kocl-) or k,.…”
Section: Influence Of the Substituentmentioning
confidence: 99%
“…From the experimental data the rate constant k3 ( k H O C I ) for molecular mechanism (reaction 7) of each amine can be calculated, the logarithm of which shows a linear relationship with the pK2 of the amine, as shown in Figure 5 (4); EA (5); nPA (6); isoPA (7); p-alanine (8); alanine (9); glycine (10); 2-amino-2-(hydroxymethyl)-1,3propandiol (11); and glycylglycine (12). and analogous equations were obtained by using kg (kocl-) or k,.…”
Section: Influence Of the Substituentmentioning
confidence: 99%
“…According to the available published findings (6,9,10) for this kind of system the reaction between MAE and hypochlorite may be written as HN(CH3)CH2CH2OH + HCIO -C1N(CH3)CH2CH20H + H20 (fast) C1N(CH3)CH2CH20H -products (slow) In the work described here NC1MAE was generated by mixing known volumes of solutions of amine and sodium hypochlorite together with a suitable quantity of NaOH solution or buffer to maintain the reaction medium at the desired working pH.…”
Section: Methodsmentioning
confidence: 99%
“…Slow reactions, of half-life longer than 5 h, were also followed iodometrically (9). The preparation of solutions and experimental method have been described in an earlier article (6).…”
Section: Methodsmentioning
confidence: 99%