Kinetics and mechanism of the oxidation of tris(2,2′-bipyridyl)- and tris(1,10-phenanthroline)-iron(II) complexes with peroxodisulphate in acetate buffers

A kinetic and mechanistic study on the oxidation of indole‐3‐acetic acid by peroxodisulfate

“…Studies on the oxidation of organic compounds and inorganic complexes by peroxodisulfate have been reported 1–11. Oxidation of indoles has received much attention due to the involvement of their resulting products in significant biological processes 12.…”

Kinetics and mechanism of oxidation of hydrazinium ion with peroxomonophosphoric acid in acid perchlorate solutions and role of trace iodide ions

“…One important difference is that the oxidation of hydroxylamine is catalyzed by Fe(II1) also whereas the present reaction is not. This is not understandable in view of the fact that hydrazine [27] and hydroxylamine [28], both are oxidized with Fe(II1) in acid medium with almost the same rate.…”

Polyethylene Glycol-Mediated Kinetic Study of Nitrodecarboxylation of α,β-Unsaturated Acids by Blau's Fe(III) Bipy Complex

“…These complexes are reported to be substitution labile and entirely different from ferridin (blue complexes of Fe(III) with Bipy), which could not be obtained by direct mixing but only by the oxidation of ferroidin and were also found to be substitution inert. In the recent past, the 2, 2′‐bipyridine ligand has been extensively used as a metal‐chelating ligand due to its robust redox stability and ease of functionalization, which became the driving force to take up kinetics and mechanistic studies of redox reactions involving [Fe(III)–2, 2′‐bipyridyl complex] and a variety of organic and inorganic compounds . Over a period of time, our group has been actively engaged in the kinetics and mechanism of redox reactions involving Fe(III) chelates formed by the direct addition of ligand such as Bipy to Fe(III) .…”