2016
DOI: 10.1088/0031-8949/t167/1/014048
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Kinetics of carbide formation in the molybdenum–tungsten coatings used in the ITER-like Wall

Abstract: The kinetics of tungsten carbide formation was investigated for tungsten coatings on CFC with a molybdenum interlayer as they are used in the ITER-like Wall in JET. The coatings were produced by combined magnetron sputtering and ion implantation. The investigation was performed by preparing focused ion beam cross sections from samples after a heat treatment in argon atmosphere. Baking of the samples was done at temperatures of 1100°C, 1200°C, and 1350°C for hold times between 30 minutes and 20 hours. It was fo… Show more

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Cited by 9 publications
(9 citation statements)
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“…935 tiles have been coated (see Figure 2), of 14 different types with embedded diagnostics (Langmuir probes, thermocouples and fiber Bragg grating). Subsequent FIB/SEM analysis of this area confirmed porosity formation at the interfaces [13], along with the carbidisation of the layers (MoC/WC/W2C) [14] as identified by STEM in previous studies [15]. The formation of tungsten carbide is a precursor of the coating delamination.…”
Section: W On Non-actively Cooled Graphite Pfcsupporting
confidence: 71%
“…935 tiles have been coated (see Figure 2), of 14 different types with embedded diagnostics (Langmuir probes, thermocouples and fiber Bragg grating). Subsequent FIB/SEM analysis of this area confirmed porosity formation at the interfaces [13], along with the carbidisation of the layers (MoC/WC/W2C) [14] as identified by STEM in previous studies [15]. The formation of tungsten carbide is a precursor of the coating delamination.…”
Section: W On Non-actively Cooled Graphite Pfcsupporting
confidence: 71%
“…This is also confirmed by the observation that all the defects appeared and evolved on an edge or a corner, and not in the centre of the tile. Moreover, the temperature and the number of cycles are too low to allow for the phenomenon of W carbidization with the formation of W 2 C and WC, brittle compounds that are likely to break under thermal loads [8,9,10].…”
Section: Results Of the Hhf Cycling Testmentioning
confidence: 99%
“…This is associated with tiles which did not fully undergo the prescribed heat treatment at the time of production. As is mentioned in [44] there is a known mechanism for failure of the coatings by carbidisation if surface temperatures exceed 1350°C for more than two hours [45]. However, this mechanism has not been identified in the samples analysed so far because the protection limit is below this temperature.…”
Section: Hot Spot On the Partly Delaminated Divertor Tilesmentioning
confidence: 94%