1999
DOI: 10.1002/aic.690450904
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Kinetics of oil dispersion in the absence and presence of block copolymers

Abstract: A phenomenological model proposed describes droplet breakup in the turbulently agitated lean oil-in-water dispersions and pro®ides a correlation between the median droplet size in an agitated

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Cited by 24 publications
(15 citation statements)
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References 19 publications
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“…Spontaneous charging of droplets can be caused by the development of a double layer due to the presence of ions dissolved in water (Lenard, 1892;Chapman, 1937Chapman, , 1938aIribane and Mason, 1967;Bailey, 1988), statistical #uctu-ation of electrolytic ion concentration among the droplets (Chapman, 1934;Dodd, 1952), contact electri"cation between the solution and the surrounding material (Vick, 1953;Byrne, 1977) and capture of ions from air (White, 1951;Liu et al, 1987;Pearse and Pope, 1977;Polat et al, 1993Polat et al, , 1996. These mechanisms may act simultaneously in charging a droplet.…”
Section: Introductionmentioning
confidence: 99%
“…Spontaneous charging of droplets can be caused by the development of a double layer due to the presence of ions dissolved in water (Lenard, 1892;Chapman, 1937Chapman, , 1938aIribane and Mason, 1967;Bailey, 1988), statistical #uctu-ation of electrolytic ion concentration among the droplets (Chapman, 1934;Dodd, 1952), contact electri"cation between the solution and the surrounding material (Vick, 1953;Byrne, 1977) and capture of ions from air (White, 1951;Liu et al, 1987;Pearse and Pope, 1977;Polat et al, 1993Polat et al, , 1996. These mechanisms may act simultaneously in charging a droplet.…”
Section: Introductionmentioning
confidence: 99%
“…The analysis is based on light scattering method. Schematic of the experimental set-up is given in another publication [4]. It contains a 2.5 l vessel of standard geometry [5] with four baffles.…”
Section: Methodsmentioning
confidence: 99%
“…(2), ρ is the density of the continuous phase, N the stirrer speed and γ the oil-water interfacial tension. Polat et al [4] developed a phenomenological emulsification model based on the study of Hinze [2]. The model, given by Eq.…”
Section: Dispersion Modelsmentioning
confidence: 99%
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“…Improved oil dispersion produces finer and finer droplets which increase the probability of collisions between particles and oil droplets which in turn increases the recovery. Polat et.al [6] studied emulsification of dodecane oil in the presence of various triblock co-polymers. It was measured that the addition of copolymers reduced the median oil droplet size significantly.…”
Section: Introductionmentioning
confidence: 99%