“…Spontaneous charging of droplets can be caused by the development of a double layer due to the presence of ions dissolved in water (Lenard, 1892;Chapman, 1937Chapman, , 1938aIribane and Mason, 1967;Bailey, 1988), statistical #uctu-ation of electrolytic ion concentration among the droplets (Chapman, 1934;Dodd, 1952), contact electri"cation between the solution and the surrounding material (Vick, 1953;Byrne, 1977) and capture of ions from air (White, 1951;Liu et al, 1987;Pearse and Pope, 1977;Polat et al, 1993Polat et al, , 1996. These mechanisms may act simultaneously in charging a droplet.…”