Kinetics of the reaction between chlorine and oleic acid in carbon tetrachloride solution

Clegg, G.T.; Winter, Pierre

doi:10.1007/bf02582528

Cited by 2 publications

(5 citation statements)

References 5 publications

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“…20 Clegg and Winter studied kinetics of the reaction between chlorine and oleic acid in carbon tetrachloride solution. 21 The process involves gas absorption with chemical reaction, which involves large heat generation. The reaction between chlorine and oleic acid is highly exothermic with negligible evaporation effect for the oleic acid.…”

Section: Case Study-absorption Of Chlorine In Oleic Acid Using Lamina...mentioning

confidence: 99%

“…According to the work of Clegg and Winter, it was expected that interfacial turbulence would not be present in this system because of the high viscosity of the oleic acid. 21 3.3. Modeling.…”

Section: Case Study-absorption Of Chlorine In Oleic Acid Using Lamina...mentioning

confidence: 99%

“…Clegg and Winter studied kinetics of the reaction between chlorine and oleic acid in carbon tetrachloride solution . The process involves gas absorption with chemical reaction, which involves large heat generation.…”

Section: Introductionmentioning

confidence: 99%

“…The reaction between chlorine and oleic acid is highly exothermic with negligible evaporation effect for the oleic acid. According to the work of Clegg and Winter, it was expected that interfacial turbulence would not be present in this system because of the high viscosity of the oleic acid …”

Section: Introductionmentioning

confidence: 99%

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Model Building Methodology for Multiphase Reaction Systems

Hiwale

Hwang²,

Smith

2011

Ind. Eng. Chem. Res.

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A new approach to reactor model building for two-phase absorption processes is developed by considering simultaneously mass and heat transfer phenomena, and chemical reaction mechanism and kinetics. In particular, the interaction of mass and heat transfer with chemical reaction over the reactor design is considered to improve the accuracy of the simulation results. A novel methodology is applied to identify suitable reaction mechanisms and kinetics based on limited experimental data. This methodology allows the engineer to develop feasible reaction mechanisms in a systematic approach. Importantly, the required scope for any further lab experiments is identified, especially when the modeling needs further clarification for the reaction kinetics or mechanisms. In this way, a more robust reactor design can be achieved by making full use of experimental information, saving unnecessary laboratory and pilot plant experiments. For a case study, chlorine absorption to oleic acid is applied to the modeling of a laminar jet absorber.

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Section: Case Study-absorption Of Chlorine In Oleic Acid Using Lamina...mentioning

confidence: 99%

Section: Case Study-absorption Of Chlorine In Oleic Acid Using Lamina...mentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

See 2 more Smart Citations

Model Building Methodology for Multiphase Reaction Systems

Hiwale

Hwang²,

Smith

2011

Ind. Eng. Chem. Res.

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“…They found that in the presence of light 9,10-dichlorostearic acid formation was accompanied by dimer and trimer formation. Clegg and Winter (1972) chlorinated oleic acid dissolved in carbon tetrachloride in the presence of light and in the temperature range 25 to 44 °C. Their results were well correlated by a kinetic model incorporating second-order addition and substitution reactions.…”

mentioning

confidence: 99%

Sperm Whale Oil Replacements from Halogenation of Jojoba Oil

Wisniak¹,

Alfandary²

1979

Ind. Eng. Chem. Prod. Res. Dev.

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Kinetics of the chlorination and bromination of jojoba oil has been studied at different temperatures, solvents, and operating conditions. Chlorination follows first-order kinetics in double bond concentration with an activation energy of -11 kcal/mol. Solvents with high dielectric constant increase the rate of reaction. Bromination involves a two-step mechanism with one or two bromine molecules per double bond; up to 0.2 s reaction time the rate is first order in each of the reagents, and afterwards it is first order in the double bonds and second order in bromine. Faster rates are obtained lowering the temperature and/or increasing the dielectric content of the solvent. The chlorinated derivative improves the load carrying capacity of the lubricating oil.

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Kinetics of the reaction between chlorine and oleic acid in carbon tetrachloride solution

Cited by 2 publications

References 5 publications

Model Building Methodology for Multiphase Reaction Systems

Model Building Methodology for Multiphase Reaction Systems

Sperm Whale Oil Replacements from Halogenation of Jojoba Oil

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