La2NiO4+δ as electrode material for solid oxide fuel cells and electrolyzer cells

Egger, Andreas; Schrödl, Nina; Gspan, Christian; Sitte, Werner

doi:10.1016/j.ssi.2016.10.002

Cited by 38 publications

(28 citation statements)

References 51 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Egger et al 28 investigated the long-term behavior of La 2 NiO 4+d as an electrode material under a Crcontaining atmosphere with convergent beam electron diffraction (CBED). They conclude that the product phase that forms upon exposure to chromium is a LaNi 1Àx Cr x O 3 perovskite.…”

Section: Chemical Chromium Poisoning Reactionmentioning

confidence: 99%

“…24,25 Because rare-earth nickelates are free of Sr and Mn, they are also considered to possess better Crpoisoning tolerance than conventional LSM or LSCF cathodes. [26][27][28][29][30] Lee et al 26 studied the Crpoisoning effect of La 2 NiO 4+d by infiltrating Cr into the symmetric cell electrode, and they reported that performance of LNO is less sensitive to Cr than LSCF although the reaction product LaCrO 3 was observed. Hou et al 29 and Lee et al 30 investigated chromium poisoning of La 2 NiO 4 and Nd 2 NiO 4+d using symmetric cells, respectively, and they showed insignificant poisoning effects on the electrode performance and microstructure.…”

Section: Introductionmentioning

confidence: 99%

“…Halfcells were cathodically polarized or held under open-circuit condition, and the ohmic and polarization resistances of the electrode were periodically characterized using galvanostatic current interruption. Different from previous studies reported by other researchers, [26][27][28][29][30] in this work, anode-supported cells (ASC) with an La 2 NiO 4+d electrode were also tested with or without current load, during which voltage-current (V-I) measurements were conducted periodically. The V-I curves were analyzed using a polarization model, and the effects of chromium poisoning on different polarization resistances of LNO electrode were studied for the first time and compared with baseline LSM electrodes.…”

Section: Introductionmentioning

confidence: 99%

See 2 more Smart Citations

Improved Tolerance of Lanthanum Nickelate (La2NiO4+δ) Cathodes to Chromium Poisoning Under Current Load in Solid Oxide Fuel Cells

Gong

Wang

Banner

et al. 2019

JOM

View full text Add to dashboard Cite

Lanthanum nickelate, La 2 NiO 4+d (LNO), is studied as a cathode material for use in solid oxide fuel cells with the objective of mitigating chromium poisoning. Under current load, both electrochemical and chemical reactions cause chromium poisoning, and high current density and humidity accelerate the poisoning. However, compared with a standard strontium-doped lanthanum manganite cathode, the LNO cathode has a much higher tolerance for chromium poisoning. This can be ascribed to a greatly reduced chromium deposition in LNO.

show abstract

Section: Chemical Chromium Poisoning Reactionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

See 1 more Smart Citation

Improved Tolerance of Lanthanum Nickelate (La2NiO4+δ) Cathodes to Chromium Poisoning Under Current Load in Solid Oxide Fuel Cells

Gong

Wang

Banner

et al. 2019

JOM

View full text Add to dashboard Cite

show abstract

“…Studies have also reported that metallic ratios and temperature have profound influences on the microstructure, composition and electrochemical property of perovskites [222,223]. Based on this, the effects of Ni/Co ratios were evaluated in a recent study by Chrzan et al [220] for a yttria-stabilized zirconia backbone with a Ce 0.…”

Section: Non-noble Metal Catalystsmentioning

confidence: 99%

Recent Progresses in Electrocatalysts for Water Electrolysis

Khan

Zhao

Zou

et al. 2018

Electrochem. Energ. Rev.

360

178

View full text Add to dashboard Cite

The study of hydrogen evolution reaction and oxygen evolution reaction electrocatalysts for water electrolysis is a developing field in which noble metal-based materials are commonly used. However, the associated high cost and low abundance of noble metals limit their practical application. Non-noble metal catalysts, aside from being inexpensive, highly abundant and environmental friendly, can possess high electrical conductivity, good structural tunability and comparable electrocatalytic performances to state-of-the-art noble metals, particularly in alkaline media, making them desirable candidates to reduce or replace noble metals as promising electrocatalysts for water electrolysis. This article will review and provide an overview of the fundamental knowledge related to water electrolysis with a focus on the development and progress of non-noble metal-based electrocatalysts in alkaline, polymer exchange membrane and solid oxide electrolysis. A critical analysis of the various catalysts currently available is also provided with discussions on current challenges and future perspectives. In addition, to facilitate future research and development, several possible research directions to overcome these challenges are provided in this article.

show abstract

“…Alternatively, La 2 NiO 4+δ (LNO) as the mixed ionic and electronic conductor (MIEC) material with the K 2 NiF 4 -type structure has been regarded as a promising candidate oxygen electrode material due to its moderate thermal expansion coefficient (~13.0×10 -6 K -1 ), high oxygen ion conductivity (~0.02 S•cm -1 at 700 o C) and favorable electrochemical performance caused by the additional two phase boundary (2PB) [9][10][11]. The crystal structure of LNO consists of alternating stacked La 2 O 3 rocksalt layers and LaNiO 3 perovskite layers along the c direction [12,13].…”

Section: Introductionmentioning

confidence: 99%

Electrochemical performance of La2NiO4+δ-Ce0.55La0.45O2-δ as a promising bifunctional oxygen electrode for reversible solid oxide cells

Yang

Tian

et al. 2020

Preprint

View full text Add to dashboard Cite

In this work, La2NiO4+δ-xCe0.55La0.45O2-δ (denoted as LNO-xLDC) with various LDC contents (x = 0, 10, 20, 30 and 40, wt %) were prepared and evaluated as bifunctional oxygen electrodes for reversible solid oxide cells (RSOCs). Compared with the pure LNO, the optimum composition of LNO-30LDC exhibited the lowest polarization resistance (Rp) of 0.53 and 0.12 Ω·cm2 in air at 650 and 750 oC, respectively. The enhanced electrochemical performance of LNO-30LDC oxygen electrode was mainly attributed to the extended triple phase boundary and more oxygen ionic transfer channels. The hydrogen electrode supported single cell with LNO-30LDC oxygen electrode displayed peak power densities of 276, 401 and 521 mW·cm-2 at 700, 750 and 800 oC, respectively. Moreover, the electrolysis current density of the single cell demonstrated 526.39 mA·cm-2 under 1.5 V at 800 oC, and the corresponding hydrogen production rate was 220.03 ml·cm-2·h-1. The encouraging results indicated that LNO-30LDC was a promising bifunctional oxygen electrode material for RSOCs.

show abstract

La2NiO4+δ as electrode material for solid oxide fuel cells and electrolyzer cells

Cited by 38 publications

References 51 publications

Improved Tolerance of Lanthanum Nickelate (La2NiO4+δ) Cathodes to Chromium Poisoning Under Current Load in Solid Oxide Fuel Cells

Improved Tolerance of Lanthanum Nickelate (La2NiO4+δ) Cathodes to Chromium Poisoning Under Current Load in Solid Oxide Fuel Cells

Recent Progresses in Electrocatalysts for Water Electrolysis

Electrochemical performance of La2NiO4+δ-Ce0.55La0.45O2-δ as a promising bifunctional oxygen electrode for reversible solid oxide cells

Contact Info

Product

Resources

About