The main target of the study is to highlight, by means of numerical simulations, the advantages and possible drawbacks of using composite materials instead of the classical cast iron to equip the brake system of railway freight vehicles. The qualitative and quantitative evaluations refer mainly to the braking capacity by considering as main parameter the stopping distance, in various operational conditions. Results indicate that composite materials are more efficient in the braking process, but in the case of low speeds, the recommendation is to perform earlier and/or stronger braking actions than usual, in classical cast iron equipment on rolling stock.