Laminar composite solid electrolyte with succinonitrile-penetrating metal-organic framework (MOF) for stable anode interface in solid-state lithium metal battery

Zhao, Ting; Kou, Weijie; Zhang, Yafang; Wu, Wenjia; Li, Wenpeng; Wang, Jingtao

doi:10.1016/j.jpowsour.2022.232349

Cited by 25 publications

(4 citation statements)

References 53 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…70 Another peak at 398.4 eV belongs to Li 3 N, which should be the decomposition product from SN. 71 Li 3 N is also considered as a favourable component of SEI because of its high ionic conductivity, which is important in reducing the interfacial resistance and inhibiting Li dendrites. 72 As the etching proceeded, chemical information of the inner surface was exposed, and the peak intensities of C-C-O, O-C-O and C-F became weakened and weakened.…”

Section: Resultsmentioning

confidence: 99%

See 1 more Smart Citation

Anin situformed copolymer electrolyte with high ionic conductivity and high lithium-ion transference number for dendrite-free solid-state lithium metal batteries

Ren

Cai

et al. 2023

J. Mater. Chem. A

View full text Add to dashboard Cite

show abstract

Section: Resultsmentioning

confidence: 99%

Section: Resultsmentioning

confidence: 99%

Anin situformed copolymer electrolyte with high ionic conductivity and high lithium-ion transference number for dendrite-free solid-state lithium metal batteries

Ren

Cai

et al. 2023

J. Mater. Chem. A

View full text Add to dashboard Cite

show abstract

“…[34] The N 1s spectrum shows peaks associated with Li 3 N and TFSI − at 398.9 and 401.0 eV (Figure 7b). [35,36] The presence of mechanically stable LiF and highly ionically conductive Li 3 N is beneficial for suppressing side reactions between Li metal and SN. [37] The Li 1s spectrum displayed five peaks at 53.8, 54.5, 55.4, 56.2, and 57.4 eV, corresponding to Li 2 O, Li 2 CO 3 , Li 3 N, LiF, and TFSI − (Figure 7c).…”

Section: Electrochemical Properties Of Vec_x-link_3sn2limentioning

confidence: 99%

Inducing an Amorphous Phase in Polymer Plastic Crystal Electrolyte for Effective Ion Transportation in Lithium Metal Batteries

Kim,

Yang,

Seo

et al. 2023

Adv Funct Materials

View full text Add to dashboard Cite

Polymer plastic crystal electrolytes (PPCEs) have garnered significant attention for addressing the challenges associated with succinonitrile (SN), including its inadequate mechanical properties and side reactions with electrodes. However, a comprehensive investigation of the influence of the molecular structure of the polymer network on the states of SN within the network and its subsequent impact on ionic conductivities remains largely unexplored. To shed light on this critical aspect, the binding energy between SN and the polymer moiety is investigated as a determining factor in the conformation and crystallization behavior of SNs, through the dispersion‐corrected density functional theory (DFT‐D) simulations. These findings reveal that variations in miscibility resulting from the effects of binding energy significantly affected the formation of the amorphous phase in PPCEs. As a result, vinyl ethylene carbonate (VEC)‐based PPCE exhibits high ionic conductivity at room temperature (2.6 × 10−3 S cm−1 at 25 °C) and possesses a completely amorphous phase, which can be attributed to the optimized miscibility among its components. The feasibility of using a high‐performance solid‐state lithium‐metal battery (LMB) configuration is also examined by combining the PPCE with LiFePO4 (LFP) and LiNi0.8Co0.1Mn0.1O2 (NCM811) cathode materials.

show abstract

“…After soaking in carbonate solution, the high density of charge carriers in channels can also facilitate Li + hopping. Different from the ionic conduction mechanism of inorganic solid-state electrolytes, in which metal ions hop through vacancies to enable the charge transfer process, the main conduction mechanism of MOFs lies in the adsorption of solution anions by metal nodes, which allows the dissociated Li + to complex and transport along [34]. Nonetheless, the flammable inner solution cannot be avoided, which leaves safety hazards unresolved, and the relatively low conductivity also limits the further application of MOFs.…”

Section: Composition and Structure Introduction Of Mofs Hybrid Electr...mentioning

confidence: 99%

Recent Advances in Ionic Liquids—MOF Hybrid Electrolytes for Solid-State Electrolyte of Lithium Battery

Lin

Jin

et al. 2023

Batteries

View full text Add to dashboard Cite

Li-ion batteries are currently considered promising energy storage devices for the future. However, the use of liquid electrolytes poses certain challenges, including lithium dendrite penetration and flammable liquid leakage. Encouragingly, solid electrolytes endowed with high stability and safety appear to be a potential solution to these problems. Among them, ionic liquids (ILs) packed in metal organic frameworks (MOFs), known as ILs@MOFs, have emerged as a hybrid solid-state material that possesses high conductivity, low flammability, and strong mechanical stability. ILs@MOFs plays a crucial role in forming a continuous interfacial conduction network, as well as providing internal ion conduction pathways through the ionic liquid. Hence, ILs@MOFs can not only act as a suitable ionic conduct main body, but also be used as an active filler in composite polymer electrolytes (CPEs) to meet the demand for higher conductivity and lower cost. This review focuses on the characteristic properties and the ion transport mechanism behind ILs@MOFs, highlighting the main problems of its applications. Moreover, this review presents an introduction of the advantages and applications of Ils@MOFs as fillers and the improvement directions are also discussed. In the conclusion, the challenges and suggestions for the future improvement of ILs@MOFs hybrid electrolytes are also prospected. Overall, this review demonstrates the application potential of ILs@MOFs as a hybrid electrolyte material in energy storage systems.

show abstract

Laminar composite solid electrolyte with succinonitrile-penetrating metal-organic framework (MOF) for stable anode interface in solid-state lithium metal battery

Cited by 25 publications

References 53 publications

Anin situformed copolymer electrolyte with high ionic conductivity and high lithium-ion transference number for dendrite-free solid-state lithium metal batteries

Anin situformed copolymer electrolyte with high ionic conductivity and high lithium-ion transference number for dendrite-free solid-state lithium metal batteries

Inducing an Amorphous Phase in Polymer Plastic Crystal Electrolyte for Effective Ion Transportation in Lithium Metal Batteries

Recent Advances in Ionic Liquids—MOF Hybrid Electrolytes for Solid-State Electrolyte of Lithium Battery

Contact Info

Product

Resources

About