3Owing to unique band structure and inherent exotic physical properties originated from Dirac fermions with linear band dispersion, Dirac materials, such as graphene [1] and topological insulators, [2] have been considered as a promising candidate for nextgeneration electronic and spintronic devices. As the emerging three-dimensional (3D)Dirac materials, Cd3As2 [3] and Na3Bi [4] have been theoretically predicted and subsequently verified by the angle-resolved photoemission spectroscopy (ARPES) [5][6][7][8] and electric transport measurments, [9][10][11][12] in which the Dirac nodes are developed via the point contact of conduction-valence bands with linear dispersion in all 3D of kspace. More importantly, 3D Dirac semimetals can be driven into various novel phases, such as Weyl semimetals, [13,14] topological insulators, [15] axion insulators, [16,17] and topological superconductors, [12] by breaking time reversal symmetry or inversion symmetry. Thus, 3D Dirac semimetal is a versatile platform for the systematic study of unusual quantum phase transitions between rich topological quantum states.[4]Compared with the air-sensitive Na3Bi, Cd3As2 tends to be much stable at room temperature with a high chemical stability against oxidation, [18] which is an ideal system for 3D Dirac materials. Soon after the first prediction in Cd3As2, [3] photoemission spectroscopy revealed a pair of 3D Dirac nodes located on the opposite sides of the Brillouin zone center (Γ point), which are protected by the C4 rotational symmetry.[5]Transport measurements show that Cd3As2 exhibits ultrahigh mobility up to 9×10 6 cm 2 V -1 s -1 at 5 K, [9] a giant linear magnetoresistance, [10] and a nontrivial Berry phase [11] owing to the linear band dispersion and concomitant Dirac fermions. Very recently, a 4 pressure-induced superconductivity was also identified in Cd3As2 crystals, making it an promising candidate for the topological superconductors. [12] All these studies relied on the high-quality crystals prepared from the time consuming Flux method, which has hindered the research expansion and future practical applications.Here, we reported a new approach -facile and scalable chemical vapor deposition We grew Cd3As2 microbelts using Cd3As2 powders as the precursor in a horizontal tube furnace. After a typical growth procedure (see methods), high-quality needle-like crystals grown on silicon substrates are observable by naked-eyes. Figure 1a is a scanning electron microscopy (SEM) image that shows the typical morphology of asgrown microbelts, from which the belt-like crystals exhibit a length up to millimeter with smooth surfaces. The typical width and thickness are up to tens of micrometers.In order to determine their crystal structure, we carried out X-ray diffraction (XRD)analysis on a single microbelt with the belt surface normal to the XRD beam. Figure 1b shows the typical XRD pattern, in which a series of sharp peaks can be indexed to 5 {n,n,2n} (where n is an integer), further verifing that the longitudinal shining surfaces are {112}...