A 40-ha field is under study in the loess hills of
southwestern
Iowa to determine the impact of corn production in
ridge-tilled soils on the nitrate-nitrogen loading in
groundwater.
Within the vadose zone, nitrate concentration between
June 1989 and December 1991 ranged from <10 to >80 mg/L. Well water concentrations increased from <5 mg/L
in 1972 to >60 mg/L in 1994. In both hydrogeologic
compart
ments, time of sampling and landscape position are
important factors influencing concentrations. The
unsaturated
zone groundwater system has a high potential for storage
of unutilized nitrogen as nitrate. Leaching resulted in
the
drinking water MCL being exceeded for several wells
screened within the saturated loess, which is
characterized
by relatively high hydraulic conductivity.
Concentrations
within and below the loess−glacial till interface did
not
exceed the standard. A conservative solute transport
model
was used to predict the concentration of nitrate exiting
the field in basin drainage. Denitrification in which
nitrate
is reduced to nitrite by autotrophic bacteria and then
further reduced geochemically to nitric oxide, nitrous
oxide,
or nitrogen may be an important mechanism for reducing
the nitrate concentration within selected landscape
positions, especially those in near proximity to the water
table. Due to its relatively rapid conductance of
both
water and applied agchemicals, the loess hills represent
a vulnerable agricultural landscape on which nitrogen
fertilization impacts groundwater quality.