The present study investigates the effects of ambient free-stream turbulence (FST) on the momentum and heat transfer in a spatially developing, turbulent flat-plate boundary layer via large-eddy simulations using the ADM-RT model. Due to a local turbulence intensity T u of 7% in the free stream, the skin-friction coefficient c f and Stanton number St are substantially elevated up to 25% and 32%, respectively, in the fully turbulent region (Re τ = 300). This observation is in qualitative agreement with earlier experimental studies. Moreover, the Reynolds analogy factor is found to increase with the FST intensity T u. The depression of both mean velocity and temperature profiles in the wake region due to FST is observed. In addition, the pre-multiplied spanwise spectra show that the outer peak residing in the logarithmic region in the case without FST is replaced by a new peak located near the boundary layer edge with a spanwise scale of about 3 − 4δ 95 . It is suggested that these large-scale events and their imprint throughout the boundary layer cause the elevation of both the skin friction and heat transfer on the solid surface.