Topological insulators are quantum materials that have an insulating bulk state and a topologically protected metallic surface state with spin and momentum helical locking and a Dirac-like band structure.(1-3) Unique and fascinating electronic properties, such as the quantum spin Hall effect, topological magnetoelectric effects, magnetic monopole image, and Majorana fermions, are expected from topological insulator materials.(4, 5) Thus topological insulator materials have great potential applications in spintronics and quantum information processing, as well as magnetoelectric devices with higher efficiency.(6, 7) Three-dimensional (3D) topological insulators are associated with gapless surface states, and two-dimensional (2D) topological insulators with gapless edge states.(8) The topological surface (edge) states have been mainly investigated by first-principle theoretical calculation, electronic transport, angleresolved photoemission spectroscopy (ARPES), and scanning tunneling microscopy (STM).(9) A variety of compounds have been identified as 2D or 3D topological insulators, including HgTe/CdTe, On the other hand, topological insulator materials also exhibit a number of excellent optical properties, including Kerr and Faraday rotation, ultrahigh bulk refractive index, near-infrared frequency transparency, unusual electromagnetic scattering and ultra-broadband surface plasmon resonances. In details, Dirac plasmon excitations have been observed in Bi 2 Se 3 micro-ribbon arrays at the THz frequency.(13) Ultraviolet and visible frequency plasmonics have been observed in nanoslit and nanocone arrays of Bi 1.5 Sb 0.5 Te 1.8 Se 1.2 crystals.(14, 15) High transparency has been observed in nanometer scale Bi 2 Se 3 nanoplates. Ultrahigh refractive index has been observed in the bulk of Bi 1.5 Sb 0.5 Te 1.8 Se 1.2 crystals and Sb 2 Te 3 thin films.(15, 16) These excellent optical properties enable topological