Large-scale synthesis of In2S3 nanosheets and their rechargeable lithium-ion battery

Ye, Fangmin; Wang, Cen; Du, Guohao; Chen, Xubin; Zhong, Yijun; Jiang, Jinlong

doi:10.1039/c1jm12937f

Cited by 61 publications

(53 citation statements)

References 27 publications

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“…Owing to the unique structural characteristics, the SnS 2 -SiO 2 nanorods may find various applications in catalysis, sensors, and energy storage. [9][10][11][12][13][14]31 For example, the intercalation/de-intercalation of lithium ions is expected to be easier and faster in layerstacked nanorod compared to its fullerene, nanotube, nanosheet, and bulk counterparts, 15 which leads to novel and/or improved performance of the SnS 2 -SiO 2 nanorod anode.…”

Section: Resultsmentioning

confidence: 99%

“…[4][5][6] More recently, the rise of graphene has also aroused general curiosity towards two-dimensional (2D) layered nanosheets. 7,8 For example, various graphene analogues of layered chalcogenides, such as WS 2 , 9 ZrS 2 , 10 MoS 2 , 11 In 2 S 3 , 12 and SnS 2 , 13,14 have been demonstrated to exhibit improved lithium storage performances owing to the high surface area and host capabilities.…”

Section: Introductionmentioning

confidence: 99%

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Layer-stacked tin disulfide nanorods in silica nanoreactors with improved lithium storage capabilities

Zhang

et al. 2012

Nanoscale

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A new structure of layered materials, layer-stacked nanorod, has been fabricated through an entirely new template-engaged structural transformation methodology. The formation of layer-stacked hexagonal tin disulfide (SnS(2)) nanorods has been demonstrated as an example by using tetragonal tin (Sn) nanorods as sacrificing templates and silica (SiO(2)) as nanoreactors. In addition, the structural transformation process probably involves the formation of orthorhombic tin sulfide (SnS) nanorods as an intermediate product. The rod-like morphology and single-crystal feature of the Sn templates are well preserved in both SnS(2) and SnS products due to the nanoscale confinement in silica. Owing to its unique structural characteristics, the SnS(2)-SiO(2) nanorod anode exhibits excellent capacity retention and improved rate capability, facilitating its application in lithium ion batteries with long cycle life and high power density.

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Section: Resultsmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Layer-stacked tin disulfide nanorods in silica nanoreactors with improved lithium storage capabilities

Zhang

et al. 2012

Nanoscale

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“…[ 20 , 21 ] The binding energies of In 3d 5/2 and In 3d 3/2 (Figure S4b , Supporting Information) are measured with peaks located at 444.5 and 452.0 eV, respectively, which indicate a trivalent oxidation state for In element. [ 22 , 23 ] As displayed in the O 1s spectrum (Figure S4c , Supporting Information), lattice oxygen peaks at 530.0, 531.9, and 532.5 eV correspond to —OH stems from In(OH) 3 , In—O, and C—O/C═O, respectively. [ 24 ] Figure S4d (Supporting Information) shows the high‐resolution XPS spectrum of the C 1s.…”

Section: Resultsmentioning

confidence: 99%

A Lamellar Yolk–Shell Lithium‐Sulfur Battery Cathode Displaying Ultralong Cycling Life, High Rate Performance, and Temperature Tolerance

et al. 2021

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The shuttling behavior and slow conversion kinetics of the intermediate lithium polysulfides are the severe obstacles for the application of lithium‐sulfur (Li‐S) batteries over a wide temperature range. Here, an engineered lamellar yolk–shell structure of In2O3@void@carbon for the Li‐S battery cathode is developed for the first time to construct a powerful barrier that effectively inhibits the shuttling of polysulfides. On the basis of the unique nanochannel‐containing morphology, the continuous kinetic transformation of sulfur and polysulfides is confined in a stable framework, which is demonstrated by using X‐ray nanotomography. The constructed Li‐S battery exhibits a high cycling capability over 1000 cycles at 1.0 C with a capacity decay rate as low as 0.038% per cycle, good rate performance, and temperature tolerance at −10, 25, and 50 °C. A nondestructive in situ monitoring method of the interfacial reaction resistance in different cycling stages is proposed, which provides a new analysis perspective for the development of emerging electrochemical energy‐storage systems.

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“…Thus, facile, economical, and effective preparation methods are still needed pressingly. Currently, wet chemical method is found to be facile and efficient for fabricating various nanostructures, owing to its many merits, such as low reaction temperature, simple operation and low cost [18]. Hence, a simple wet 4 chemical method under reflux condition to obtain CdS nanostructures is highly desirable.…”

Section: Introductionmentioning

confidence: 99%

Facile synthesis of CdS nanorods with enhanced photocatalytic activity

Chen

Jia

Cao

et al. 2015

Ceramics International

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Large-scale synthesis of In2S3 nanosheets and their rechargeable lithium-ion battery

Cited by 61 publications

References 27 publications

Layer-stacked tin disulfide nanorods in silica nanoreactors with improved lithium storage capabilities

Layer-stacked tin disulfide nanorods in silica nanoreactors with improved lithium storage capabilities

A Lamellar Yolk–Shell Lithium‐Sulfur Battery Cathode Displaying Ultralong Cycling Life, High Rate Performance, and Temperature Tolerance

Facile synthesis of CdS nanorods with enhanced photocatalytic activity

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