To enhance the friction and wear performance of TC4 titanium alloy, micro‐arc oxidation(MAO) coating was fabricated on its surface, which was subsequently sealed with a modified graphene/epoxy resin coating to form a composite coating of micro‐arc oxidation ‐modified graphene/epoxy resin. The friction and wear performance of samples sealed by different methods are analyzed and characterized using a scanning electron microscope, an energy spectrometer, and friction and wear tester. The results indicate that the modified graphene/epoxy resin coating successfully combines with the micro‐arc oxidation coating and fills the pores, thereby enhancing the friction and wear performance of the composite coating. In tribological tests, compared with other samples, this composite coating has a lower friction coefficient and specific wear rate, showing excellent friction and wear performance, and its main wear mechanism is adhesive wear. Therefore, the fabrication of a micro‐arc oxidation ‐modified graphene/epoxy resin composite coating can improve the friction and wear performance of TC4 titanium alloy.