This contribution investigates a novel laser ignition method based on a dual-pulse resonant pre-ionization scheme. The first laser pulse efficiently creates initial gas ionization (seed electrons) through a 2 + 1 resonantly-enhanced multiphoton ionization (REMPI) scheme targeting molecular oxygen (λ ~ 287.6 nm). This pulse is followed by a second non-resonant near-infrared pulse (λ = 1064 nm) for energy addition into the gas via inverse bremsstrahlung absorption. The sequence of two pulses creates a laser induced plasma that exhibits high peak electron number density and temperature (ne ~ 8 × 1017 cm-3 at t = 100 ns and T ~ 8000 K at t = 10 μs, respectively). These plasma parameters are similar to those attained for typical single-pulse near-infrared laser plasmas but with the advantage of substantially lower pulse energy (by factor of ~ 2.5) in the dual-pulse REMPI case. A combustion study focusing on ignition of propane/air mixtures shows that the dual-pulse REMPI method leads to an extension of the lean flammability limit, and an increase in combustion efficiency near the lean limit, as compared to laser ignition with a single NIR pulse. The measurement results and observed gas dynamics are discussed in the context of their impact on combustion applications.