Laser-induced fluorescence spectra of jet cooled p-chlorobenzyl radical

Jet Spectroscopy of theD122B1–D012B1Transition of thep-Cyanobenzyl Radical

“…detail elsewhere (36,37,40). The p-cyanobenzyl radical was generated by ArF laser photolysis of a-bromo-p-methylbenzonitrile (a-bromo-p-cyanotoluene).…”

“…The experimental setup used in this study is described in 2 Following Mulliken (38), and in accordance with our earlier work (34)(35)(36)(37), the symmetry and out-of-plane axes are labeled z and y, respectively. detail elsewhere (36,37,40).…”

Spectroscopic Evidence of Jet-Cooled p-Chloro-α-Methylbenzyl Radical in Corona Excitation

“…Nevertheless, all three isomers of chlorobenzyl radicals have been clearly identified using techniques of laser induced fluorescence (LIF) 10 and electric DC discharge.…”

Vibronic Emission Spectra of Jet-Cooled o-Cyanobenzyl Radical

“…[7][8][9][10][11] Weakly emitting chlorobenzyl radicals have been recently identified from the vibronic emission spectra, in which the sequence of electronic energy of the lowest excited electronic state exhibits similar tendency to those of chlorotoluenes. [12][13][14][15][16] Cyanobenzyl radicals are also interesting species in spectroscopy due to the electron-rich substituent. The analysis of the vibronic bandshape of the p-cyanobenzyl radical has revealed that the lowest excited electronic state is 2 B 2 which is different from other types of benzyl radicals.…”