We present results of the first attempt to produce arrays of sharp Silicon Carbide (SiC) electron emitters by ultraviolet pulsed‐laser processing of single‐crystal SiC surfaces. This simple one‐step technique, performed under controlled pressure of a reactive gas, has demonstrated efficient silicon cold cathodes both in terms of current density and of emission threshold. SiC has been found to produce the best emitters when treated in air. The corresponding cathodes have a lower emission threshold and produce higher current densities than their Si‐based counterparts. The role of surface morphology on the electron emission properties obtained is discussed in comparison to silicon. (© 2008 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)