LaSrFeO4 nanopowders synthesized by different combustion methods: Effect of fuel/particle size

Singh, Suram; Singh, Devinder

doi:10.1016/j.ceramint.2016.07.032

Cited by 8 publications

(7 citation statements)

References 34 publications

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“…The reaction is quick and reduces the time for the agglomeration of small particles necessary for high power density cells. 128 The GNP-varied NVP cell has been utilized in previous research for fuel cell fabrication. 97 The research work shows the proof-of-concept study that NVP-GNP cells have high energy performance up to 102 mAh g −1 at 20 C. Furthermore, optimization with glucose-derived hard carbons (GDHCs) can minimize the capacity and sloping region of electrode potential.…”

Section: ■ Electrospinningmentioning

confidence: 99%

Research Progress on Electrochemical Properties of Na₃V₂(PO₄)₃ as Cathode Material for Sodium-Ion Batteries

Kang

Liu

et al. 2023

Ind. Eng. Chem. Res.

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The polyanion sodium vanadium phosphate Na3V2(PO4)3 (NVP) belongs to the sodium superionic conductors (NASICON) material. Its NASICON structural backbone forms a stable sodium accommodation site, and the open three-dimensional ion transport channel is conducive to the rapid intercalation/deintercalation of Na ions. As a cathode material for batteries, Na3V2(PO4)3 has an extremely high specific capacity, voltage plateau, and cycle stability, meeting the requirements of low cost and high safety. It is a large-scale energy storage material with ideal potential and has received extensive attention. However, the low electronic conductivity of Na3V2(PO4)3 material hinders its further application. Based on the current demand for large-scale application of sodium-ion batteries, this paper re-examines the effect of existing research progress on promoting practical applications and the problems that need to be solved in the future from the perspective of raw material cost system and process complexity. The paper first introduces the structural characteristics of Na3V2(PO4)3 material and the mechanism of sodium-ion intercalation/deintercalation. Then it introduces the synthesis methods, such as the sol–gel method, hydrothermal method, and solid-phase reaction method. In addition, it summarizes the modification studies of Na3V2(PO4)3, including carbon coating, ion doping and, morphology control, design of composite materials and structures based on Na3V2(PO4)3. Finally, it discusses the possible future development of Na3V2(PO4)3.

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Section: ■ Electrospinningmentioning

confidence: 99%

Research Progress on Electrochemical Properties of Na₃V₂(PO₄)₃ as Cathode Material for Sodium-Ion Batteries

Kang

Liu

et al. 2023

Ind. Eng. Chem. Res.

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“…Firstly, all the reactants will be dissolved, which ensures intimate mixing of the ions and is crucial to ensure formation of pure phases [16]. Secondly, the reaction is very quick, which reduces time for particle agglomeration and enables the production of small particles [17] that are necessary for high-power density battery cells. Thirdly, this method can be turned into a flow process, which makes it industrially scalable [13].…”

Section: Synthesis Of Na 3 V 2 (Po 4 )mentioning

confidence: 99%

“…Thirdly, this method can be turned into a flow process, which makes it industrially scalable [13]. The GNP and its variations have been used by the solid-oxide fuel cell research community [13,17,18] and to some extent by the battery community to synthesize and study materials like NaTi3(PO4)3 [19], Li(Ni1/3Mn1/3Co1/3-xNax)O2 [20], LiNi1/3Co1/3Mn1/3O2 (urea as fuel) [21], Li4Ti5O12 (lactic acid as fuel) [22], substituted Na0.44MnO2 bronzes [23][24][25][26], Na0.44MnO2 (urea as fuel) [27] and ZnFe2O4 [28]. This paper is the first report to our knowledge that successfully utilizes the GNP method to produce a NVP cathode material and characterize it in half and full cells.…”

Section: Synthesis Of Na 3 V 2 (Po 4 )mentioning

confidence: 99%

Glycine-Nitrate Process for Synthesis of Na3V2(PO4)3 Cathode Material and Optimization of Glucose-Derived Hard Carbon Anode Material for Characterization in Full Cells

et al. 2019

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Cost-effective methods need to be developed to lower the price of Na-ion battery (NIB) materials. This paper reports a proof-of-concept study of using a novel approach to the glycine-nitrate process (GNP) to synthesize sodium vanadium phosphate (Na3V2(PO4)3 or NVP) materials with both high-energy (102 mAh g−1 at C/20) and high-power characteristics (60 mAh g−1 at 20 C). Glucose-derived hard carbons (GDHCs) were optimized to reduce both sloping and irreversible capacity. The best results were achieved for electrodes with active material heat treated at 1400 °C and reduced Super P additive. Sloping region capacity 90 mAh g−1, irreversible capacity 47 mAh g−1, discharge capacity 272 mAh g−1 (of which plateau 155 mAh g−1) and 1st cycle coulombic efficiency (CE) 85% were demonstrated. GDHC||NVP full cell achieved 80 mAh g−1 (reversible) by NVP mass out of which 60 mAh g−1 was the plateau (3.4 V) region capacity. Full cell specific energy and energy density reached 189 Wh kg−1 and 104 Wh dm−3, respectively. After 80 cycles, including rate testing from C/20 to 10 C, the cell cycled at 65 mAh g−1 with 99.7% CE. With further optimization, this method can have very high industrial potential.

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“…Perovskites are usually prepared at high temperatures so another important field of research is aimed at reducing energy consumption of the synthesis [13]. Combustion synthesis routes, which involve low cost materials, short processing time and produce large amount of gases that inhibit particle size growth, are of great interest in synthesizing nano-size powders with high specific surface area [14]. In this type of synthesis, the combustion velocity, the choice of the combustible substance and its amount are very important factors that influence the final properties of the obtained powder [15].…”

Section: Introductionmentioning

confidence: 99%

Combustion synthesis and characterization of Ln1−xMxCr0.9Ni0.1O3 (Ln = La and/or Nd; M = Sr and/or Ca; x ≤ 0.25) perovskites for SOFCs anodes

Ortega-San-Martín

Morán-Ruiz

Wain-Martin

et al. 2018

Ceramics International

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A series of chromite perovskites with the general formula Ln 1−x M x Cr 0.9 Ni 0.1 O 3 (Ln = La and/or Nd; M = Sr and/or Ca; x ≤ 0.25) has been prepared by three combustion synthesis routes using a different combustible substance each time: glycine, urea and sucrose. In order to isolate the effect of divalent dopant concentration from the A cation steric effects, the whole group has a fixed mean A cation radius, < r A > ≈ 1.22 Å, and cation size disorder, σ 2 (r A) ≈ 0.0001 Å 2 , but variable doping x. Their crystal structure, microstructure, electrical properties and expansion coefficients have been investigated on the basis of their possible use as anode materials for intermediate temperature solid oxide fuel cells (SOFC). Cell parameters, grain sizes, expansion coefficients and conductivities all are found to be dependent on x and the combustible substance used. The most interesting relationship is the negative dependence of the conductivity with x under H 2 atmosphere: conductivity decreases with doping which is the opposite to the expected behavior for a p-type doped perovskites and has not been reported before.

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LaSrFeO4 nanopowders synthesized by different combustion methods: Effect of fuel/particle size

Cited by 8 publications

References 34 publications

Research Progress on Electrochemical Properties of Na₃V₂(PO₄)₃ as Cathode Material for Sodium-Ion Batteries

Research Progress on Electrochemical Properties of Na₃V₂(PO₄)₃ as Cathode Material for Sodium-Ion Batteries

Glycine-Nitrate Process for Synthesis of Na3V2(PO4)3 Cathode Material and Optimization of Glucose-Derived Hard Carbon Anode Material for Characterization in Full Cells

Combustion synthesis and characterization of Ln1−xMxCr0.9Ni0.1O3 (Ln = La and/or Nd; M = Sr and/or Ca; x ≤ 0.25) perovskites for SOFCs anodes

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LaSrFeO4 nanopowders synthesized by different combustion methods: Effect of fuel/particle size

Cited by 8 publications

References 34 publications

Research Progress on Electrochemical Properties of Na3V2(PO4)3 as Cathode Material for Sodium-Ion Batteries

Research Progress on Electrochemical Properties of Na3V2(PO4)3 as Cathode Material for Sodium-Ion Batteries

Glycine-Nitrate Process for Synthesis of Na3V2(PO4)3 Cathode Material and Optimization of Glucose-Derived Hard Carbon Anode Material for Characterization in Full Cells

Combustion synthesis and characterization of Ln1−xMxCr0.9Ni0.1O3 (Ln = La and/or Nd; M = Sr and/or Ca; x ≤ 0.25) perovskites for SOFCs anodes

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Research Progress on Electrochemical Properties of Na₃V₂(PO₄)₃ as Cathode Material for Sodium-Ion Batteries

Research Progress on Electrochemical Properties of Na₃V₂(PO₄)₃ as Cathode Material for Sodium-Ion Batteries