Rapid identification of structural damage positions is essential to the post-disaster rehabilitation of structures and infrastructures. Large shear deformation, e.g., shear failure of bridge piers, shear-slip of slopes, and shear cracking of structural walls, is often the cause of structural instability. Distributed optical fibre sensing (DOFS) techniques have an advantage over point-based sensors in terms of spatial continuous structural condition monitoring. This paper presents the development of new measurement theory and algorithm to evaluate the structural shear deflection based on the large beam deflection and optical bend loss theories. The proposed technique adopted a photon-counting Optical Time Domain Reflectometer (ν-OTDR) with polymer optical fibres (POFs) which has a large deformation measurement range and high spatial resolution. In the experiment, shear deformation events can be successfully detected and evaluated from the proposed technique. When the normalised shear deformation is larger than 0.2, both the event locations and the magnitudes can be accurately determined. When normalised shear deformation is lesser than 0.2, the error in the magnitude evaluation increased, but the event location can be found with an absolute error <0.5 m. Multiple shear events can be treated as independent events when they are separated by more than 5 m. Various configurations of POFs attached to concrete beam specimens for rupture failure monitoring were also studied. The configuration that could maximise the POF curvature at the beam failure produced the largest ν-OTDR signals. In other configurations in which the POFs were only stretched at failure, the signals were less strong and were influenced by the POF-structure bonding strength.Sensors play a crucial role in detecting the health of the structure and accessing the probable damage or collapse. Over the past few decades, studies on optical fibre have started, consequently leading to the proposal of various ideas and techniques for structural health monitoring and damage detection [3][4][5][6][7][8][9][10][11]. Innovative distributed optical fibre sensors (DOFS) [9,12] are used over classical strain gauges to monitor the structural damage and preferred as a better alternatives because of the following reasons: (a) strain gauges are point sensors whereas DOFSs are continuous sensors along the entire length; (b) deployment of strain gauges requires the prior knowledge of expected damage locations; (c) installation of miniature strain gauges involves cumbersome gluing and wire welding processes; and (d) each strain gauge is connected to a pair of cables, and it can be quite disordered if a large number of strain gauges are required.Habel and Bismarck [5] recommended the use of highly resolvable bare and plasma-polymer coated fibre sensors in concrete environment. These sensors could reliably measure the micro-deformation behaviour of special grouts. Abbiati et al. [6] proposed a prototype of an optical fibre sensor for monitoring civil engineering structures par...