Layer-by-layer assembly of ordered organic–inorganic luminescent film toward sensoring nitrobenzene compound

Molecular design confirmation for proposition of improved photophysical properties in a dye-intercalated layered double hydroxides

“…Series of the uorescence dye molecules intercalated in the LDH materials exhibited several new photophysical properties compared with those of the pristine dye systems. 46 Recently some researchers have reported that the emission spectrum of the uorescence dye molecules intercalated into LDH exhibited a red or blue shi compared with that of a dilute solution. [67][68][69] Furthermore, it was demonstrated that the luminescent properties and the molecule arrangement of the dyes can be tuned to some extent aer intercalation into the LDH layer.…”

“…Moreover, the TFs display a fast luminescence response as the colorimetric chemosensor for the sensing applications. 46 Recently some researchers have reported that the organic dye anions/LDH systems exhibit blue-shi photoemission and enhanced uorescence efficiency compared with those of the pristine azo dye sample, and the azo dye/LDH thin lms exhibit precise polarized luminescence with the uorescence anisotropy characterization.…”

Layered Double Hydroxide Nanosheets on Plasmonic Arrays of Al Nanocylinders for Optical Sensing

“…23 These properties of LDHs satisfy the prerequisite as a constituent of optical sensors. Actually, LDHs with optical transparency in the visible region, such as ZnAl and MgAl systems, are used for fluorescence sensing of vitamins, 24 explosive compounds, 25 pollution, 26 temperatures, 27 and cations, 28 as well as optical biosensors, 29,30 and as a protein immobilization substrate. 30 In those systems, utilizing their high adsorption ability, LDHs are used as a host material for fluorescent probes which give a backgroundless luminescent signal.…”

Highly Selective Bifunctional Luminescent Sensor toward Nitrobenzene and Cu2+ Ion Based on Microporous Metal–Organic Frameworks: Synthesis, Structures, and Properties

“…Metal–organic frameworks (MOFs), also being defined as microporosity-containing coordination polymers, have aroused immense focal interests recently, which are built on the inherent strong coordination of the linkers to the metal centers, and this strong coordinative bond always contributes to form rigid, stable, crystalline functional materials amenable to applications development in many respects, such as gas storage or separation, molecular fluorescence sensor, magnetic properties, drug delivery, etc. − Among diverse applications, fluorescence sensors closely related to luminescent MOFs are of great concern on account of their higher selectivity, sensitivity, and operability. − …”