“…Similarly, as plotted in Figure d, the V CPD values of lines 1–3 at the edge of the single-layer WS 2 flake, as marked in Figure c, are ∼206, ∼208, and ∼211 mV, respectively, and the work function of the monolayer WS 2 crystal is calculated to be ∼4.692 eV. Therefore, a bilayer WS 2 flake exhibits ∼0.05 eV higher work function than that of a monolayer WS 2 crystal, and the increasing work function with the increase of layer number is also mentioned in the reported literature of MoS 2 and WS 2 crystals with different layer numbers, which is explained by the interlayer screening effect. − The surface potential of thin films is screened by a substrate-induced electric field. With the increase of layer number of 2D TMDC crystals, the screening effect will gradually weaken and the surface potential shows a decreasing trend too close to bulk values.…”