“…[ 1,2 ] In recent years, perovskite oxide heterostructures have attracted a lot of attention due to its potential applications compared with traditional p–n junctions. [ 3–6 ] As perovskite oxides have exotic electronic states, [ 7–9 ] the heterostructures which is composed of perovskite oxides, show plenty of interesting physical properties, such as rectifying characteristics, [ 10,11 ] photovoltaic effect, [ 12–14 ] positive colossal magnetoresistance, [ 15,16 ] resistive switching effect, [ 17 ] and so on. Numerous perovskite oxide heterostructures were developed for compound functional application, such as all‐oxide diode, memristor, solar cell, photodetector, and so on.…”