1983
DOI: 10.1002/oms.1210180111
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Cited by 8 publications
(3 citation statements)
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“…For example, the Cr(CO)'; ion reacts with the substrates to a minor extent by loss of an HCO' radical. Loss of a radical from the collision complex is not anomalous for Cr(CO); which reacts likewise with other substrates, for example, esters, ethers [14], and methanol [12]. As shown in earlier reports, not only crCCO)S-, but also the Mn(CO)S-and Fe(CO)i ions, are very reactive toward a number of substrates including alkanes [12, 31,32].…”
Section: Instrumentationmentioning
confidence: 86%
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“…For example, the Cr(CO)'; ion reacts with the substrates to a minor extent by loss of an HCO' radical. Loss of a radical from the collision complex is not anomalous for Cr(CO); which reacts likewise with other substrates, for example, esters, ethers [14], and methanol [12]. As shown in earlier reports, not only crCCO)S-, but also the Mn(CO)S-and Fe(CO)i ions, are very reactive toward a number of substrates including alkanes [12, 31,32].…”
Section: Instrumentationmentioning
confidence: 86%
“…The loss of CH 30H results, of course, in addition of a CO ligand to the reactant ion with concomitant increase in the coordination number of the ion. Addition of a CO ligand to the reactant ion has been reported also for the reactions of Cr(CO)i\ with aldehydes [14], which proceeds in part by alkane elimination. More recently, it has been observed also in the reactions of Mn(CO)i\ and Fe(CO)2 with methanol [12,13] in which two hydrogen molecules are expelled from the collision complex and in the reactions of Fe(CO)2 with larger primary alcohols (C nH Zn + 10H, n = 2-6) in which H 2 and an alkane (C n -1H 2n ) are eliminated with formation of Fe(CO); [45].…”
Section: Loss Ofch 30hmentioning
confidence: 91%
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