The emission of greenhouse gases poses enormous pressure on current carbon emissions and carbon reduction. Accurate quantification of carbon emissions from coal-fired power plants is of great significance for achieving the dual carbon goal. To enable enterprises to better understand their carbon emissions, this study constructs a carbon emission model and carbon emission data accounting model for coal-fired power plants. Case data calculations and a carbon emission reduction analysis were conducted. The experiment showcases that the carbon sensitivity of the inner side of the boiler under control conditions is higher than that of the operating parameters controlled on the inner side of the steam turbine, with a maximum total value of 16.67 g/MJ; the annual average low calorific value of coal remains between 16,000 kJ/kg; the activity level of coal remains between 30,000 TJ; and the oxidation probability of coal char during combustion fluctuates, with a maximum of 99.8%. In the calculation of coal-fired carbon emissions, the fitting difference between the emissions of generator unit 1 and generator unit 2 is maintained within 2%. Overall, the CO2 emissions of power plants involved in the study are generally high. The model built through this study has well analyzed the carbon emissions of power plants. It is of great significance for the actual carbon emission reduction of coal-fired power plants.