Ligand hierarchy on driving the crystal packing. Effect of supramolecular interactions on solid-state conformations adopted by saccharinate Pd(ii) complexes

Quadrol-Pd(ii) complexes: phosphine-free precatalysts for the room-temperature Suzuki–Miyaura synthesis of nucleoside analogues in aqueous media

“…CvO groups show short non-covalent intramolecular contacts with two OH groups (O⋯O distances: 2.721(4) Å and 2.770(5) Å). In saccharinate complexes, it has been reported that CvO group produces shorter supramolecular interactions than SO 2 , 35 the Scheme 2 One pot synthesis of ( 2) and ( 3) in methanol.…”

Water‐Soluble Pd‐Imidate Complexes as Versatile Catalysts for the Modification of Unprotected Halonucleosides

“…[43] As very initial results, we presented the application of novel Pd-saccharinate complexes in Suzuki-Miyaura cross-coupling of different aryl and benzyl bromides with aryl boronic acids. [41] Their excellent performance in comparison with related compounds, [44] and the confirmation of its singular properties coordinating palladium, [45] put saccharine at the forefront of our efforts developing new catalytic systems, [46] that eventually found application in the modification of nucleosides.…”